2-ethyl-acrylic acid pentyl ester | 78450-89-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-ethyl-acrylic acid pentyl ester
• 英文别名: 2-Aethyl-acrylsaeure-pentylester；Pentyl 2-methylidenebutanoate
• CAS: 78450-89-2
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: VXTGKNNMZJLQLM-UHFFFAOYSA-N

物化性质

• 沸点：
  68 °C(Press: 1.5 Torr)
• 密度：
  1.4311 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-ethyl-acrylic acid pentyl ester 、 1-amino-4-benzylidene-2-phenyl-1H-imidazol-5(4H)-one 在 lead(IV) acetate 作用下， 以 二氯甲烷 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  Deshmukh, M. B.; Chavan, P. B., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 12, p. 1337 - 1339

  摘要：

  DOI：
• 作为产物：
  描述：

  戊醇 、 2-乙基丙烯酰氯 以95%的产率得到2-ethyl-acrylic acid pentyl ester
  参考文献：
  名称：

  Marshalok, G.A.; Yatchishin, I. I.; Tolopko, D. K., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 4, p. 603 - 608

  摘要：

  DOI：

文献信息

• Method of making heat curable adhesive coated insulation for transformers
  申请人：WESTINGHOUSE ELECTRIC CORPORATION

  公开号：EP0012542A1

  公开（公告）日：1980-06-25

  Flexible resin adhesive-coated substrates made by coating a sheet material with a wet, heat reactive adhesive resin, containing a monomer and an amount of an ultraviolet radiation sensitive photoinitiator effective to cause polymerization of monomer in response to ultraviolet radiation, and applying ultraviolet radiation to the adhesive resin coating on the sheet material to polymerize monomer without the application of heat, forming a dry, uncured coating of adhesive bonded to the sheet material.

  柔性树脂粘合剂涂层基材，其制作方法是在片状材料上涂覆湿的、热反应性的粘合剂树脂，该树脂含有单体和一定量的紫外线辐射敏感光引发剂，在紫外线辐射下可有效地引起单体聚合，并对片状材料上的粘合剂树脂涂层进行紫外线辐射，使单体聚合而无需加热，从而形成粘合在片状材料上的干的、未固化的粘合剂涂层。
• Process for coating thermoplastic substrates with a coating composition containing a non-aggressive solvent
  申请人：——

  公开号：US20010053417A1

  公开（公告）日：2001-12-20

  A process for coating a thermoplastic substrate which comprises applying a solvent based coating composition to the substrate and curing the coating composition at ambient temperature to 125° C. to form a uniform smooth film on the substrate; wherein the coating composition contains about 45-80% by weight of a film forming binder and 20-55% by weight of an organic liquid carrier; wherein the binder contains (A) 40-90% by weight, based on the weight of the binder, of a polymer selected from the following: acrylic polyol, polyester polyol, polyether polyol or a polyurethane polyol; and (B) 10-60% by weight, based on the weight of the binder, of an organic polyisocyanate crosslinking agent; and wherein the organic liquid carrier used in the coating composition comprises at least 50% by weight, based on the weight of the organic liquid carrier used in the coating composition, of tertiary butyl acetate; the process of this invention also can be used to apply lacquers, i.e., coating composition that do not contain a crosslinking agent such as a polyisocyanate.

  一种涂覆热塑性基材的工艺，包括将溶剂型涂料组合物涂覆到基材上，并在环境温度至 125°C 下固化涂料组合物，以便在基材上形成均匀光滑的薄膜； 其中涂层组合物含有约 45-80%（按重量计）的成膜粘合剂和 20-55%（按重量计）的有机液体载体；其中粘合剂含有 (A) 以粘合剂重量计，40-90%（以重量计）选自下列的聚合物：丙烯酸多元醇、聚酯多元醇、聚醚多元醇或聚氨酯多元醇；和 (B) 10-60%（以粘合剂重量计）的有机多异氰酸酯交联剂；以及 本发明的工艺也可用于涂漆，即不含多异氰酸酯等交联剂的涂料组合物。
• Copolymers comprising low surface tension (meth) acrylates
  申请人：——

  公开号：US20030096929A1

  公开（公告）日：2003-05-22

  The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.

  本发明涉及一种共聚物，它包括第一种可辐射聚合的低表面张力（甲基）丙烯酸酯单体和一种或多种其他可辐射聚合的乙烯基不饱和单体。共聚物的多分散指数小于 2.5。本发明还包括一种制造上述低表面张力共聚物的受控自由基聚合方法。该方法包括以下步骤：将第一种可自由基聚合的低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的乙烯基不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中。
• Coating compositions which contain a low surface tension (meth) acrylate containing block copolymer flow control agent
  申请人：——

  公开号：US20030100675A1

  公开（公告）日：2003-05-29

  A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl (meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.

  一种热固性组合物，包括具有官能团的第一反应物；具有与第一反应物官能团共反应的官能团的第二反应物；以及嵌段共聚物流动控制剂。嵌段共聚物包括由可辐射聚合的氟烷基（甲基）丙烯酸酯单体残留物组成的第一嵌段、由第二种可辐射聚合的乙烯基不饱和单体残留物组成的第二嵌段，以及可选的由第三种可辐射聚合的乙烯基不饱和单体残留物组成的第三嵌段。第一、第二和第三嵌段由彼此不同的残基组成，嵌段共聚物的多分散指数小于 2.5。还公开了一种涂覆基材的方法，包括以下步骤：将本热固性组合物涂覆到基材上；凝聚热固性组合物以形成基本连续的薄膜；以及通过加热固化所述热固性组合物。
• Low surface tension (meth) acrylate containing block copolymer prepared by controlled radical polymerization
  申请人：——

  公开号：US20030114593A1

  公开（公告）日：2003-06-19

  A block copolymer including a block of residues of a low surface tension (meth)acrylate monomer; a block of residues of a monomer free of hydroxyl group and amine group residues; and, optionally, a third block of residues of a monomer free of hydroxyl groups and amine groups. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. A controlled radical polymerization method is disclosed to make the low surface tension block copolymers. The method includes the steps of sequentially adding a first monomer composition that is free of hydroxyl groups and amine groups and a second monomer composition that includes the low surface tension monomer to a suitable atom transfer radical polymerization initiator and polymerizing the monomer compositions to form a block copolymer.

  一种嵌段共聚物，包括一个低表面张力（甲基）丙烯酸酯单体残留物嵌段；一个不含羟基和胺基残留物的单体残留物嵌段；以及可选的第三个不含羟基和胺基的单体残留物嵌段。第一、第二和第三嵌段由彼此不同的残基组成，嵌段共聚物的多分散指数小于 2.5。公开了一种制造低表面张力嵌段共聚物的受控自由基聚合方法。该方法包括以下步骤：将不含羟基和胺基的第一单体组合物和包括低表面张力单体的第二单体组合物依次加入到合适的原子转移自由基聚合引发剂中，并使单体组合物聚合形成嵌段共聚物。