2-ethoxythiocarbonylthiopropionic acid 3-(4-formylphenyloxy)propyl ester | 479421-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-ethoxythiocarbonylthiopropionic acid 3-(4-formylphenyloxy)propyl ester
• 英文别名: 3-(4-Formylphenoxy)propyl 2-ethoxycarbothioylsulfanylpropanoate；3-(4-formylphenoxy)propyl 2-ethoxycarbothioylsulfanylpropanoate
• CAS: 479421-13-1
• 化学式: C₁₆H₂₀O₅S₂
• 分子量: 356.464
• InChiKey: VBHKBMVKNPNIRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  23
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-(3-羟基丙氧基)苯甲醛 在 吡啶 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 4.0h， 生成 2-ethoxythiocarbonylthiopropionic acid 3-(4-formylphenyloxy)propyl ester
  参考文献：
  名称：

  Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

  摘要：

  The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy H-1 monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(02)00526-4

文献信息

• Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin
  作者：Anne-Claude Dublanchet、Marie Lusinchi、Samir Z Zard

  DOI：10.1016/s0040-4020(02)00526-4

  日期：2002.7

  The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy H-1 monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker. (C) 2002 Published by Elsevier Science Ltd.