2-[[3,5-Bis(phenylmethoxy)phenyl]methoxy]-4,6-dichloro-1,3,5-triazine | 945456-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-[[3,5-Bis(phenylmethoxy)phenyl]methoxy]-4,6-dichloro-1,3,5-triazine
• 英文别名: 2-[[3,5-bis(phenylmethoxy)phenyl]methoxy]-4,6-dichloro-1,3,5-triazine
• CAS: 945456-17-7
• 化学式: C₂₄H₁₉Cl₂N₃O₃
• 分子量: 468.339
• InChiKey: PDWMIDICMCYCGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-[[3,5-Bis(phenylmethoxy)phenyl]methoxy]-4,6-dichloro-1,3,5-triazine 、 4-[2-(叔丁氧羰基)乙基]-4-氨基戊烷二甲酸二叔丁酯 在 N,N-二异丙基乙胺 作用下， 以 丙酮 为溶剂， 反应 48.0h， 以64%的产率得到Ditert-butyl 4-[[4-[[3,5-bis(phenylmethoxy)phenyl]methoxy]-6-chloro-1,3,5-triazin-2-yl]amino]-4-[3-[(2-methylpropan-2-yl)oxy]-3-oxopropyl]heptanedioate
  参考文献：
  名称：

  Redox Active, Hybrid Dendrimers Containing Fréchet- and Newkome-Type Blocks

  摘要：

  A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Frechet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Frechet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s(-1).

  DOI：

  10.1021/ol0708525
• 作为产物：
  描述：

  三聚氯氰 、 3,5-二苄氧基苯甲醇 在 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 以53%的产率得到2-[[3,5-Bis(phenylmethoxy)phenyl]methoxy]-4,6-dichloro-1,3,5-triazine
  参考文献：
  名称：

  Redox Active, Hybrid Dendrimers Containing Fréchet- and Newkome-Type Blocks

  摘要：

  A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Frechet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Frechet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s(-1).

  DOI：

  10.1021/ol0708525

文献信息

• Redox Active, Hybrid Dendrimers Containing Fréchet- and Newkome-Type Blocks
  作者：Wei Wang、Hao Sun、Angel E. Kaifer

  DOI：10.1021/ol0708525

  日期：2007.7.1

  A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Frechet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Frechet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s(-1).