pentene-4 oate de cyclohexyle | 117508-84-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: pentene-4 oate de cyclohexyle
• 英文别名: Cyclohexyl pent-4-enoate
• CAS: 117508-84-6
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: PXXXMNDCOYZIGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-[(difluoromethyl)thio]-2,3,5,6-tetrafluoropyridine 、 pentene-4 oate de cyclohexyle 在 fac-Ir(ppy)₃ 作用下， 以 二甲基亚砜 为溶剂， 反应 18.0h， 以70%的产率得到cyclohexyl 6,6-difluoro-4-[(perfluoropyridin-4-yl)thio]hexanoate
  参考文献：
  名称：

  氟代烷基硫化物作为烯烃双官能化的光氧化还原活性偶联剂。

  摘要：

  描述了烯烃的可见光促进的氟代烷基化-硫醇化。4-四氟吡啶基硫基片段在引发步骤中用作光氧化还原活性基团并经历自由基基团转移，这对于反应效率很重要。在初级产物中，吡啶基硫基取代基可通过自由基过程或芳族取代反应进一步官能化。

  DOI：

  10.1039/d0cc04617e
• 作为产物：
  描述：

  4-戊烯酰氯 、 环己醇 生成 pentene-4 oate de cyclohexyle
  参考文献：
  名称：

  Bourgeois, M. J.; Montaudon, E.; Maillard, B., Bulletin des Societes Chimiques Belges, 1988, vol. 97, # 4, p. 255 - 262

  摘要：

  DOI：

文献信息

• Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical Addition Reaction
  作者：Oleg V. Fedorov、Sofya I. Scherbinina、Vitalij V. Levin、Alexander D. Dilman

  DOI：10.1021/acs.joc.9b01649

  日期：2019.9.6

  The atom transfer radical addition reaction catalyzed by triphenylphosphine and copper(I) halide is described. The reaction proceeds under irradiation with 365 nm light using a light-emitting diode and was performed in regular glassware. The proposed mechanism involves the formation of quaternary phosphonium salt, which undergoes single electron reduction by copper(I) salt via photo-induced electron

  描述了由三苯基膦和卤化铜（I）催化的原子转移自由基加成反应。该反应在使用发光二极管的365nm光的照射下进行，并且在常规玻璃器皿中进行。所提出的机理涉及形成季phospho盐，该季phospho盐通过光诱导的电子转移被铜（I）盐进行单电子还原。该方法适用于末端烯烃和活化的有机卤化物，例如溴乙酸和碘乙酸与溴乙腈的酯。宝石-Difluorinated苯乙烯，为此原子转移反应是罕见的，也被证明是用于该膦/铜催化协议的良好底物。
• [EN] ALICYCLIC MUSK FRAGRANCE COMPOUNDS<br/>[FR] COMPOSÉS ALICYCLIQUES DE PARFUM MUSQUÉ
  申请人：SYMRISE AG

  公开号：WO2020125993A1

  公开（公告）日：2020-06-25

  The present invention primarily relates to the use of a compound according to the general formula (I) wherein i) m is 1, n is 1, o is 0 or 1, Y is Hydrogen, or ii) m is 2, n is 0, o is 1, Y is methyl, and wherein X is O or methylene, R and R1 are each methyl or form together with the carbon atom attached to a carbonyl group, and R2 is methyl, ethyl, propyl, butyl, butan-2-one-4-yl, tetrahydrofuran-2-yl, or tetrahydrofuran-3-yl, as perfuming ingredients. Moreover, the present invention relates to perfume compositions and perfumed products comprising the before mentioned perfuming ingredients. Still more particularly, the invention relates to a method for producing said perfumed products and a method of imparting and/or increasing musk odor characteristics to perfumed products. This invention also relates to a process for the preparation of said compounds according to the general formula (I).

  本发明主要涉及使用符合一般式(I)的化合物，其中i）m为1，n为1，o为0或1，Y为氢，或ii）m为2，n为0，o为1，Y为甲基，X为O或亚甲基，R和R1分别为甲基或与连接到羰基的碳原子形成一起的，R2为甲基、乙基、丙基、丁基、丁酮-2-基、四氢呋喃-2-基或四氢呋喃-3-基，作为香料成分。此外，本发明涉及包含上述香料成分的香水组合物和带有香水成分的香水产品。更具体地，本发明涉及生产所述香水产品的方法以及赋予和/或增加香水产品的麝香气味特征的方法。本发明还涉及根据一般式(I)制备所述化合物的方法。
• [EN] PERFUMING INGREDIENTS WITH LILY OF THE VALLEY NOTE<br/>[FR] INGRÉDIENTS PARFUMANTS PRÉSENTANT UNE NOTE DE MUGUET
  申请人：SYMRISE AG

  公开号：WO2020098923A1

  公开（公告）日：2020-05-22

  The present invention primarily relates to the use of 3-(4-isobutyl-2-methyl-cyclohexyl)pro- panal, 3-(4-Isobutyl-6-methyl-cyclohexa-1,5-dien-1-yl)propanal, 3-(4-isobutyl-6-meth- ylene-cyclohexen-1-yl)propanal, or 3-(4-isobutyl-6-methyl-cyclohexen-1-yl)propanal as perfuming ingredients. Moreover, the present invention relates to perfume compositions and perfumed products comprising the before mentioned perfuming ingredients. Still more particularly, the invention relates to a method for producing said perfumed products and a method of imparting and/or increasing i) floral and/or ii) green and/or iii) lily of the valley odor characteristics to perfumed products. This invention also relates to 3-(4-isobutyl-2- methyl-cyclohexyl)propanal, 3-(4-Isobutyl-6-methyl-cyclohexa-1,5-dien-1-yl)propanal, 3- (4-isobutyl-6-methylene-cyclohexen-1-yl)propanal, or 3-(4-isobutyl-6-methyl-cyclohexen- -yl)propanaland a process for the preparation of said compounds.

  本发明主要涉及将3-(4-异丁基-2-甲基环己基)丙醛、3-(4-异丁基-6-甲基环己-1,5-二烯-1-基)丙醛、3-(4-异丁基-6-亚甲基-环己烯-1-基)丙醛或3-(4-异丁基-6-甲基-环己烯-1-基)丙醛用作香料成分。此外，本发明涉及包含上述香料成分的香水组合物和香水产品。更具体地，本发明涉及一种生产所述香水产品的方法以及赋予和/或增加i) 花香和/或 ii) 绿色和/或 iii) 铃兰花香特性给香水产品的方法。本发明还涉及3-(4-异丁基-2-甲基环己基)丙醛、3-(4-异丁基-6-甲基-环己-1,5-二烯-1-基)丙醛、3-(4-异丁基-6-亚甲基-环己烯-1-基)丙醛或3-(4-异丁基-6-甲基-环己烯-1-基)丙醛以及制备所述化合物的方法。
• 2-(5-ISOPROPYL-2-METHYL-CYCLOHEX-2-EN- 1-YL-)ACETALDEHYDE AND 2-(6-ISOPROPYL- 3-METHYL-CYCLOHEX-2-EN-1-YL-) ACETALDEHYDE AS NEW ODORANTS
  申请人：SYMRISE AG

  公开号：US20220033338A1

  公开（公告）日：2022-02-03

  The present invention relates to novel compounds of formula (I) as well as mixtures comprising or consisting of compounds of formula (I). Furthermore, the present invention relates to a process for the preparation of the compounds of formula (I) and to the use of the compounds of formula (I) as a perfuming ingredient, in particular as a lily of the valley perfuming ingredient. Ultimately, the present invention relates to perfume preparations and perfumed products or consumer goods comprising at least one of the compounds of formula (I).

  本发明涉及公式（I）的新化合物，以及包含或由公式（I）化合物组成的混合物。此外，本发明还涉及制备公式（I）化合物的方法，以及将公式（I）化合物用作香料成分，特别是用作铃兰香料成分的用途。最终，本发明涉及香水配制品和含有公式（I）化合物之一的香水产品或消费品。
• ENCAPSULATES
  申请人：SMETS Johan

  公开号：US20130039962A1

  公开（公告）日：2013-02-14

  The present application relates to encapsulates, compositions, products comprising such encapsulates, and processes for making and using such encapsulates. Such encapsulates comprise a core comprising a perfume and a shell that encapsulates said core, such encapsulates may optionally comprise a parametric balancing agent, such shell comprising one or more azobenzene moieties.

  本申请涉及封装、组合物、包含这种封装物的产品以及制备和使用这种封装物的过程。这种封装物包括一个包含香水的核心和封装该核心的外壳，这种封装物可以选择性地包含参数平衡剂，该外壳包括一个或多个偶氮苯基团。