3-(1-苯基-3-P-苯甲基-1H-吡唑-4-YL)-败脂酸 | 63904-57-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 3-(1-苯基-3-P-苯甲基-1H-吡唑-4-YL)-败脂酸
• 英文名称: bicyclo[2.2.1]hept-5-ene-2,3-dialdehyde
• 英文别名: Bicyclo[2.2.1]hept-5-ene-2,3-dicarbaldehyde
• CAS: 63904-57-4；138752-95-1；102589-32-2
• 化学式: C₉H₁₀O₂
• 分子量: 150.177
• InChiKey: UYNITBWLFPWZLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(1-苯基-3-P-苯甲基-1H-吡唑-4-YL)-败脂酸 、 苯胺 在 sodium acetate 作用下， 以 氯仿 为溶剂， 反应 24.0h， 以50%的产率得到4,7-二氢-2-苯基-4,7-甲桥异吲哚
  参考文献：
  名称：

  A new synthesis of methanoisoindoles

  摘要：

  DOI：

  10.1134/s1070428012040264
• 作为产物：
  描述：

  1,3,3a,4,7,7-alpha-六氢-1,3-二甲氧基-4,7-甲烷异苯并呋喃 在 盐酸 作用下， 以 水 为溶剂， 反应 0.5h， 生成 3-(1-苯基-3-P-苯甲基-1H-吡唑-4-YL)-败脂酸
  参考文献：
  名称：

  A new synthesis of methanoisoindoles

  摘要：

  DOI：

  10.1134/s1070428012040264

文献信息

• CINCHONA-BASED BIFUNCTIONAL ORGANOCATALYSTS AND METHOD FOR PREPARING CHIRAL HEMIESTERS USING THE SAME
  申请人：SONG Choong Eui

  公开号：US20110213151A1

  公开（公告）日：2011-09-01

  The present invention relates to cinchona-based bifunctional organocatalysts and methods for preparing chiral hemiesters using the same. More specifically, the present invention relates to methods for preparing chiral hemiesters from prochiral or meso cyclic acid anhydrides via desymmetrization, using bifunctional cinchona alkaloid catalysts comprising sulfonamide functional groups.

  本发明涉及基于金鸡纳碱的双功能有机催化剂以及利用其制备手性半酯的方法。更具体地，本发明涉及利用含有磺酰胺功能团的双功能金鸡纳碱生催化剂，通过非对称化从原消旋或中性环酸酐制备手性半酯的方法。
• USE OF METAL-ACCUMULATING PLANTS FOR THE PREPARATION OF CATALYSTS THAT CAN BE USED IN CHEMICAL REACTIONS
  申请人：Grison Claude

  公开号：US20120316340A1

  公开（公告）日：2012-12-13

  The use of metal-accumulating plants for implementing chemical reactions.

  利用富集金属的植物来实施化学反应。
• Polyolefins incorporating functional groups, masked functional group-containing monomers, reaction mixtures, and methods for preparing same
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0295076A1

  公开（公告）日：1988-12-14

  Polymers of olefin monomers and a substantially uniform concentration of carboxyl, hydroxyl, thio, amino, cabonyl and imino functional group-containing monomers. Polymers of olefin monomers and carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers substantially devoid of halogen. Method for preparing polymers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds to form masked, functional group-containing monomers and polymerizing polymer chain monomers with the masked, functional group-­containing monomers to produce a polymer chain. Method for forming masked, functional group-containing monomers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds. Masked, carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers.

  烯烃单体与浓度基本一致的含羧基、羟基、硫基、氨基、羰基和亚氨基官能团单体的聚合物。烯烃单体和含羧基、羟基、硫基、氨基、羰基和亚氨基官能团单体的聚合物，基本上不含卤素。制备聚合物的方法：使含羧基、羟基、硫基、氨基、羰基和亚氨基官能团的单体与非卤代有机金属化合物反应，形成含官能团的掩蔽单体，并使聚合物链单体与含官能团的掩蔽单体聚合，生成聚合物链。通过含羧基、羟基、硫基、氨基、羰基和亚氨基官能团的单体与非卤代有机金属化合物反应形成含官能团的遮蔽单体的方法。含羧基、羟基、硫基、氨基、羰基和亚氨基官能团的遮蔽单体。
• ENERGY-SENSITIVE RESIN COMPOSITION
  申请人：Tokyo Ohka Kogyo Co., Ltd.

  公开号：EP3275940A1

  公开（公告）日：2018-01-31

  The present invention provides an energy-sensitive resin composition with which it is possible, even if the precursor polymer is heat-treated at low temperatures, to produce a film or molded article comprising an imide ring-containing polymer having excellent heat resistance, tensile elongation and chemical resistance with a low dielectric constant, or a film or molded article comprising an oxazole ring-containing polymer having excellent heat resistance, tensile elongation and chemical resistance. Also provided are a method of manufacturing the film or molded article; a method of forming a pattern using the energy-sensitive resin composition; and a permanent film having excellent heat resistance, tensile elongation and chemical resistance. The energy-sensitive resin composition comprises an imidazole compound (A) represented by formula (1a), a resin precursor component (B), and a solvent (S), wherein the resin precursor component (B) is at least one resin precursor component selected from the group consisting of: a monomer component comprising a diamine compound represented by formula (2), a dicarbonyl compound represented by formula (3a) and/or a tetracarboxylic acid dianhydride represented by formula (3b); and a precursor polymer having a repeating unit represented by formula (4).

  本发明提供了一种能量敏感树脂组合物，使用该组合物，即使在低温下对前体聚合物进行热处理，也可以生产出一种薄膜或模塑制品，该薄膜或模塑制品由具有优异耐热性、拉伸伸长率和耐化学性且介电常数较低的含亚胺环聚合物组成，或由具有优异耐热性、拉伸伸长率和耐化学性的含恶唑环聚合物组成。此外，还提供了一种制造薄膜或模塑品的方法；一种使用能量敏感树脂组合物形成图案的方法；以及一种具有优异耐热性、拉伸伸长率和耐化学性的永久性薄膜。能敏树脂组合物包括由式 (1a) 表示的咪唑化合物 (A)、树脂前体组分 (B) 和溶剂 (S)，其中树脂前体组分 (B) 是至少一种选自以下组别的树脂前体组分：由式（2）代表的二胺化合物、式（3a）代表的二羰基化合物和/或式（3b）代表的四羧酸二酐组成的单体组分；以及具有式（4）代表的重复单元的前体聚合物。
• LIQUID COMPOSITION, QUANTUM DOT-CONTAINING FILM, OPTICAL FILM, LUMINESCENT DISPLAY ELEMENT PANEL, AND LUMINESCENT DISPLAY DEVICE
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP3812805A1

  公开（公告）日：2021-04-28

  The present invention provides: a liquid composition which can be suitably used for production of an optical film having a favorable fluorescence efficiency and includes quantum dots (A), a quantum dot-containing film obtained by drying and/or curing the liquid composition, an optical film for a light-emitting display element made of the quantum dot-containing film, a light-emitting display element panel including the optical film, and a light-emitting display equipped with the light-emitting display element panel. An ionic liquid (B), and a solvent (S) are incorporated into a liquid composition including quantum dots (A), in which the solvent (S) includes a solvent (S1), the solvent (S1) being a compound having a cyclic skeleton and including a heteroatom other than a hydrogen atom and a carbon atom.

  本发明提供：一种可适当用于生产具有良好荧光效率且包括量子点（A）的光学薄膜的液体组合物、一种通过干燥和/或固化该液体组合物而获得的含量子点薄膜、一种由该含量子点薄膜制成的用于发光显示元件的光学薄膜、一种包括该光学薄膜的发光显示元件面板，以及一种配备有该发光显示元件面板的发光显示器。在包括量子点（A）的液体组合物中加入离子液体（B）和溶剂（S），其中溶剂（S）包括溶剂（S1），溶剂（S1）是具有环状骨架并包括除氢原子和碳原子之外的杂原子的化合物。