bis<4-(chlorocarbonyl)phenyl>methane | 3268-26-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis<4-(chlorocarbonyl)phenyl>methane
• 英文别名: 4,4'-bis-(chlorocarbonyl)-diphenylmethane；4,4'-methanediyl-di-benzoyl chloride；4,4'-Methandiyl-di-benzoylchlorid；4,4'-diphenylmethane dicarboxylic acid dichloride；bis(4-chlorocarbonylphenyl)methane；4,4'-methylenedibenzoyl chloride；4-[(4-Carbonochloridoylphenyl)methyl]benzoyl chloride
• CAS: 3268-26-6
• 化学式: C₁₅H₁₀Cl₂O₂
• 分子量: 293.149
• InChiKey: ZZMXJPDWAPOGDM-UHFFFAOYSA-N

物化性质

• 熔点：
  110-111 °C(Solv: ligroine (8032-32-4))
• 沸点：
  417.1±38.0 °C(Predicted)
• 密度：
  1.322±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis<4-(chlorocarbonyl)phenyl>methane 在 lithium aluminium tetrahydride 、 sodium ethanolate 作用下， 以 四氢呋喃 、 氯苯 为溶剂， 反应 74.0h， 生成 双(4-(羟甲基)苯基)甲烷
  参考文献：
  名称：

  Gruetzmacher, Hans-Friedrich; Mehdizadeh, Ahmed; Muelverstedt, Astrid, Chemische Berichte, 1994, vol. 127, # 6, p. 1163 - 1166

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯-4,4-二羧酸 在 氯化亚砜 作用下， 生成 bis<4-(chlorocarbonyl)phenyl>methane
  参考文献：
  名称：

  Cl35 nuclear quadrupole resonance spectra of some carboxylic acid chlorides

  摘要：

  DOI：

  10.1007/bf00863204

文献信息

• Macro Rings. III. The Synthesis of [2.1.1.1]Paracyclophane
  作者：Toshio Kawato、Takahiko Inazu、Tamotsu Yoshino

  DOI：10.1246/bcsj.44.200

  日期：1971.1

  Two new macrocyclic compounds, I and II, which incorporate, respectively, four or eight benzene rings and intervening methylene bridges attached to their para positions, were synthesized. The UV, IR, and NMR spectra of these paracyclophanes were compared with a corresponding open-chain compound, III.

  合成了两种新的大环化合物 I 和 II，它们分别包含四个或八个苯环和中间连接到对位的亚甲基桥。将这些对环芳烃的 UV、IR 和 NMR 光谱与相应的开链化合物 III 进行比较。
• Nitrile imines
  申请人：Hercules Incorporated

  公开号：US04247474A1

  公开（公告）日：1981-01-27

  Disclosed are polyfunctional nitrile imines having the formula selected from R----C.tbd.N.sup..sym. --N.sup..crclbar. --R').sub.x and R----N.sup..crclbar. --N.sup..sym. .tbd.C--R").sub.x where R is an alkylene, cycloalkylene, arylene, alkyl-arylene, arylene-dialkylene, alkylene-diarylene or cycloalkylene-dialkylene radical; R' is a hydrogen, alkyl, cycloalkyl, aryl, alkaryl, or aralkyl radical; R" is an alkyl, cycloalkyl, aryl, alkaryl or aralkyl radical and x is greater than 1; and their hydrogen chloride salts having the formula selected from ##STR1## where R, R', R" and x are as defined above.

  本发明涉及一种多官能团腈亚胺，其化学式选自R----C.tbd.N.sup..sym. --N.sup..crclbar. --R').sub.x和R----N.sup..crclbar. --N.sup..sym. .tbd.C--R").sub.x，其中R是烷基，环烷基，芳基，烷基芳基，芳基二烷基，烷基二芳基或环烷基二烷基基团；R'是氢，烷基，环烷基，芳基，烷基芳基或芳基烷基基团；R"是烷基，环烷基，芳基，烷基芳基或芳基烷基基团，x大于1；以及它们的氢氯酸盐，其化学式选自##STR1##其中，R、R'、R"和x如上所定义。
• CROSSLINKED POLYAMIDE
  申请人：DESBOIS PHILIPPE

  公开号：US20110288258A1

  公开（公告）日：2011-11-24

  A process for crosslinking polyamide comprises a diisocyanate or a diacyl halide being reacted with a lactam A at a temperature of from (−30) to 150° C. and next reacting with a lactam B, a catalyst and an activator at a temperature of from 40 to 240° C.

  一种交联聚酰胺的过程包括将二异氰酸酯或二酰卤与内酰胺A在(-30)至150℃的温度下反应，然后在40至240℃的温度下与内酰胺B、催化剂和活化剂反应。
• Organopolysiloxane-grafted polybenzobisoxazoles and method for preparing same
  申请人：DOW CORNING ASIA, Ltd.

  公开号：EP0641831A1

  公开（公告）日：1995-03-08

  An organopolysiloxane-grafted polybenzobisoxazole and a method for the preparation thereof are disclosed, said polybenzobisoxazole comprising repeat units having formulas (VI) and (VII), wherein the repeat unit (VI)/repeat unit (VII) molar ratio is in the range of 100/0 to 1/99 in which A¹ denotes a tetravalent aromatic group, A² denotes a divalent organopolysiloxane group having the formula (VIII) in which R¹ denotes a divalent organic group having at least 2 carbon atoms, R² through R⁶ independently denote monovalent organic groups, n is an integer having a value of at least 1 and m is 1 or 2 and A³ comprises at least one group selected from reactive side chain-free divalent aromatic groups and reactive side chain-substituted divalent aromatic groups, with the proviso that the molar ratio of reactive side chain-free divalent aromatic groups to reactive side chain-substituted divalent aromatic groups is in the range of 100/0 to 0/100.

  本发明公开了一种有机聚硅氧烷接枝的聚苯并二异噁唑及其制备方法，所述聚苯并二异噁唑包括具有式（VI）和（VII）的重复单元，其中重复单元（VI）/重复单元（VII）的摩尔比范围为 100/0 至 1/99 其中 A¹ 表示四价芳香基团、 A² 表示具有式 (VIII) 的二价有机聚硅氧烷基团 其中 R¹ 表示至少有 2 个碳原子的二价有机基团，R² 至 R⁶ 独立地表示一价有机基团，n 是至少为 1 的整数，m 是 1 或 2，以及 A³ 包括至少一个选自无反应侧链二价芳香基团和反应侧链取代二价芳香基团的基团，但无反应侧链二价芳香基团与反应侧链取代二价芳香基团的摩尔比在 100/0 至 0/100 之间。
• POLYDIALKYLSILOXANE / POLYAMIDE COPOLYMER, PROCESS FOR PRODUCING THE SAME, AND VARIOUS MATERIALS
  申请人：NOF CORPORATION

  公开号：EP1116740A1

  公开（公告）日：2001-07-18

  A novel polydialkylsiloxane/polyamide copolymer which is excellent in biocompatibility, mechanical strength, and heat moldability, applicable for use in medical materials, ophthalmic materials, cosmetics, and electronic materials, and has a main chain represented by the formula (4), one end represented by the formula (5) and another end represented by the formula (6):         - (NH-A-NHCO-B-CO)m-     (4)         -NH-A-NH-X2     (5)         -X1     (6) wherein the ratio of -R1-(Si(R2) (R3)-O)n1-Si(R2) (R3)-R1-as A to the divalent organic group having 1 to 20 carbon atoms as A is within the range of 1:0.01 ∼ 100, and the proportion of X1 and X2 being hydrogen atoms is 10% or less relative to all the end groups, a process for producing the same, and a variety of its uses.

  一种新型聚二烷基硅氧烷/聚酰胺共聚物，具有优异的生物相容性、机械强度和热成型性，适用于医疗材料、眼科材料、化妆品和电子材料，其主链由式（4）表示，一端由式（5）表示，另一端由式（6）表示： - (NH-A-NHCO-B-CO)m- (4) -NH-A-NH-X2 (5) -X1 (6) 其中作为 A 的-R1-(Si(R2) (R3)-O)n1-Si(R2) (R3)-R1- 与作为 A 的具有 1 至 20 个碳原子的二价有机基团的比例在 1:0.01 ∼ 100 的范围内，且相对于所有末端基团，X1 和 X2 为氢原子的比例为 10%或更少，以及生产该物质的工艺及其各种用途。