N-(p-nitrobenzoyl)-L-phenylglicine | 63013-15-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(p-nitrobenzoyl)-L-phenylglicine
• 英文别名: (4-nitro-benzoyl)-(l(+)-α-amino-phenylacetic acid )；(4-Nitro-benzoyl)-(l(+)-α-amino-phenylessigsaeure)；(2S)-2-[(4-nitrobenzoyl)amino]-2-phenylacetic acid
• CAS: 63013-15-0；108583-86-4
• 化学式: C₁₅H₁₂N₂O₅
• 分子量: 300.271
• InChiKey: KKRVOLQYNMANNM-ZDUSSCGKSA-N

物化性质

• 沸点：
  575.1±50.0 °C(Predicted)
• 密度：
  1.401±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  112
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N-(p-nitrobenzoyl)-L-phenylglicine 在 三乙胺 、 2-硝基苯甲酰氯 作用下， 生成 2-(p-nitrophenyl)-4-phenyl-Δ2-oxazolone-5
  参考文献：
  名称：

  Aromatic acid chlorides dosage with N-acyl-aminoacids in aprotic solvents by a spectrophotometric method

  摘要：

  The proposed method consists essentially in the treatment of an aromatic acid chloride solution with certain amounts of N-acyl-aminoacid as reagent. The mechanism of the colored chemical reaction is described here and the concentration of the aromatic acid chloride is determined on the basis of Bouguer-Lambert-Beer law. The results are discussed having in view the electrostatic interactions in the liquid solution in which the reaction takes place. The proposed method offers a high sensitivity, accuracy, easiness and quickness of the operations. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2010.04.001
• 作为产物：
  描述：

  L-苯甘氨酸 、 4-硝基苯甲酰氯 在 sodium carbonate 作用下， 生成 N-(p-nitrobenzoyl)-L-phenylglicine
  参考文献：
  名称：

  Ingersoll; Adams, Journal of the American Chemical Society, 1922, vol. 44, p. 2936

  摘要：

  DOI：

文献信息

• Ingersoll; Adams, Journal of the American Chemical Society, 1922, vol. 44, p. 2936
  作者：Ingersoll、Adams

  DOI：——

  日期：——
• Aromatic acid chlorides dosage with N-acyl-aminoacids in aprotic solvents by a spectrophotometric method
  作者：Sunel Valeriu、Dorohoi Dana-Ortansa、Moise Mihaela、Stroia Luminita

  DOI：10.1016/j.molliq.2010.04.001

  日期：2010.7

  The proposed method consists essentially in the treatment of an aromatic acid chloride solution with certain amounts of N-acyl-aminoacid as reagent. The mechanism of the colored chemical reaction is described here and the concentration of the aromatic acid chloride is determined on the basis of Bouguer-Lambert-Beer law. The results are discussed having in view the electrostatic interactions in the liquid solution in which the reaction takes place. The proposed method offers a high sensitivity, accuracy, easiness and quickness of the operations. (C) 2010 Elsevier B.V. All rights reserved.