9-(3-(10-(naphthalen-2-yl)anthracen-9-yl)phenyl)-9H-carbazole | 1310481-54-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9-(3-(10-(naphthalen-2-yl)anthracen-9-yl)phenyl)-9H-carbazole
• 英文别名: 9-[3-(10-Naphthalen-2-ylanthracen-9-yl)phenyl]carbazole
• CAS: 1310481-54-9
• 化学式: C₄₂H₂₇N
• 分子量: 545.683
• InChiKey: JBZAWTAIOWGHCA-UHFFFAOYSA-N

物化性质

• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  43
• 可旋转键数：
  3
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-(3-溴苯基)-9H-咔唑 、 10-(2-萘基)蒽-9-硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 4.0h， 以70%的产率得到9-(3-(10-(naphthalen-2-yl)anthracen-9-yl)phenyl)-9H-carbazole
  参考文献：
  名称：

  基于10萘并蒽衍生物的高效OLED蓝光发射材料

  摘要：

  一系列新的发蓝色光的材料：2-（10-（萘-2-基）蒽-9-基）吡啶（1）；1-（10-（萘-2-基）蒽-9-基）异喹啉（2）; 9-（3-（10-（萘-2-基）蒽-9-基）苯基）-9H-咔唑（3）; 9-（4-（10-（萘-2-基）蒽-9-基）苯基）-9H-咔唑（4）；9-（4-（10-（萘-1-基）蒽-9-基）苯基）-9H-咔唑（5）；9-（4'-（10-（萘-2-基）蒽-9-基）联苯-4-基）-9H-咔唑（6）; 和9-（4' - （10-（萘-1-基）蒽-9-基）联苯-4-基）-9H-咔唑（7），设计并合成通过铃木交叉偶联反应。为了探索这些材料的电致发光特性，按以下顺序制造了多层OLED：ITO / 4,4'-双（N-（1-萘基）-N-苯基氨基）联苯（NPB）（50 nm）/蓝-发射材料（1–7）（30 nm）/ 4,7-二苯基-1,10-菲咯啉（Bphen）（30 nm）/喹啉锂（Liq）（2

  DOI：

  10.1016/j.orgel.2010.02.009

文献信息

• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2423179A1

  公开（公告）日：2012-02-29

  An aromatic amine derivative represented by the following formula (1): wherein A1 is a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted heterocyclic group or an organic group represented by the following formula (2): wherein X1, X2 and X3 are independently a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; X1 and X2 are linkage groups which are different from each other; and B1, B2 and B3 are independently a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group.

  以下是由以下式（1）表示的芳香胺衍生物： 其中A1是取代或未取代的烷基，取代或未取代的芳香基，取代或未取代的杂环基或由以下式（2）表示的有机基： 其中X1、X2和X3分别是取代或未取代的芳香基或取代或未取代的杂环基； X1和X2是彼此不同的连接基；以及 B1、B2和B3分别是取代或未取代的芳香基或取代或未取代的杂环基。
• Anthracene and carbazole based asymmetric fluorescent materials for high-efficiency deep-blue non-doped organic light emitting devices with CIEy=0.06
  作者：Zhengqin Wang、Tingting Yang、Shufan Dong、Zhengjie Wen、Huixia Xu、Yanqin Miao、Hua Wang、Junsheng Yu

  DOI：10.1016/j.dyepig.2021.110047

  日期：2022.3

  derivatives exhibited deep blue emission in toluene solution and thin film. Their electroluminescent performances was investigated by fabricating non-doped organic light-emitting diodes (OLEDs), exhibiting deep-blue emission with peaks at 444, 440 and 448 nm. The device performance based on pCzAnN as the emitter achieved a low turn-on voltage of 3.3 V, external quantum efficiency of 6.0%, deep-blue emission

  深蓝色发光材料在光电子领域有着重要的应用。然而，由于固有的宽能隙，它们的高色纯度的发展面临着巨大的挑战。在此，通过调整蒽与咔唑的连接位置，设计并合成了三种蒽基荧光材料（p CzAnN、m CzAnN和3CzAnN）。这三种扭曲的蒽衍生物在甲苯溶液和薄膜中表现出深蓝色发射。通过制造非掺杂有机发光二极管 (OLED) 来研究它们的电致发光性能，显示出深蓝色发射，峰值位于 444、440 和 448 nm。基于p CzAnN的器件性能 由于发射器实现了 3.3 V 的低开启电压、6.0% 的外部量子效率、444 nm 的深蓝色发射，具有良好的色纯度 CIE 坐标 (0.15, 0.07) 和 50 nm 的窄半峰全宽.
• Light-Emitting Device Material and Light-Emitting Device
  申请人：Murase Seiichiro

  公开号：US20070247063A1

  公开（公告）日：2007-10-25

  The present invention is a light emitting device material characterized by containing an anthracene compound represented by the following general formula (1) or general formula (3), and the present invention allows a light emitting device having high luminous efficiency and excellent durability. (R 1 to R 10 are a hydrogen atom, alkyl group, cycloalkyl group, heterocyclic group or the like. At least one of the R 1 to R 10 is a substituent represented by the following general formula (2).) (R 11 to R 18 are a hydrogen atom, alkyl group and cycloalkyl group. X is an oxygen atom or sulfur atom, and Y is a single bond; arylene group or heteroarylene group. Any one of the R 11 to R 18 is used for linking with Y, and α is used for linking with the anthracene skeleton.) (R 19 to R 37 are a hydrogen atom, alkyl group, cycloalkyl group, heterocyclic group or the like. n is 1 or 2. A is a heteroarylene group or arylene group. Any one of the R 19 to R 27 and any one of the R 28 to R 37 are used for linking with A.)

  本发明涉及一种发光装置材料，其特征在于含有以下通式（1）或通式（3）所代表的蒽化合物，本发明可实现高发光效率和优异耐久性的发光装置。（其中R1至R10为氢原子、烷基、环烷基、杂环基或类似基团。R1至R10中至少一个是以下通式（2）所代表的取代基。）（R11至R18为氢原子、烷基和环烷基。X为氧原子或硫原子，Y为单键、芳基或杂芳基。R11至R18中的任意一种用于与Y连接，α用于与蒽骨架连接。）（R19至R37为氢原子、烷基、环烷基、杂环基或类似基团。n为1或2。A为杂芳基或芳基。R19至R27中的任意一种和R28至R37中的任意一种用于与A连接。）
• MATERIAL FOR LIGHT-EMITTING ELEMENT AND LIGHT EMITTING ELEMENT
  申请人：Sugimoto Kazunori

  公开号：US20090066245A1

  公开（公告）日：2009-03-12

  The present invention is a light-emitting device material characterized by containing a pyrene compound represented by the following general formula (1): wherein R1 to R10 are specific functional groups, provided that at least one of the R1 to R10 is a substituent represented by the following general formula (2): wherein R11 to R14 are specific functional groups, provided that any one of the R11 to R14 is used for a single bond with a pyrene skeleton; X1 is a group represented by the following general formula (3): wherein R15 is a specific functional group; and Y1 to Y4 is selected from among a nitrogen atom and a carbon atom, provided that at least one of the Y1 to Y4 is a nitrogen atom and at least one thereof is a carbon atom, and no substituents exist on the nitrogen atom in the case of the nitrogen atom. This material provides a light-emitting device having high luminous efficiency and excellent durability.

  本发明是一种发光装置材料，其特征在于包含以下通式（1）所表示的芘化合物，其中R1至R10是特定的功能基团，但至少其中之一是以下通式（2）所表示的取代基：其中R11至R14是特定的功能基团，但其中任意一个用于与芘骨架形成单键；X1是以下通式（3）所表示的基团：其中R15是特定的功能基团；Y1至Y4从氮原子和碳原子中选择，但至少一个是氮原子，且其中至少一个是碳原子，在氮原子的情况下不存在取代基。该材料提供了具有高发光效率和优异耐久性的发光装置。
• Aromatic amine derivative and organic electroluminescent element using same
  申请人：Mizuki Yumiko

  公开号：US20110297923A1

  公开（公告）日：2011-12-08

  An aromatic amine derivative represented by the following formula (1): wherein at least one of R 1 to R 8 is a group other than a hydrogen atom, Ar 1 to Ar 4 are a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms.

  一种芳香胺衍生物，其化学式表示为（1）：其中至少一个R1到R8是除氢原子外的基团，Ar1到Ar4是具有6到30个环状碳原子的取代或未取代芳基基团。