3-(2-氨基-4-甲基苯氧基)丙烷-1-磺酸 | 79392-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 3-(2-氨基-4-甲基苯氧基)丙烷-1-磺酸
• 英文名称: 3-(2-amino-4-methylphenoxy)propan-1-sulfonic acid
• 英文别名: 3-(2-amino-4-methylphenoxy)propane-1-sulfonic acid；3-(2-Amino-4-methylphenoxy)propanesulphonic acid
• CAS: 79392-40-8
• 化学式: C₁₀H₁₅NO₄S
• 分子量: 245.299
• InChiKey: XPVVBMXZTSOIQD-UHFFFAOYSA-N

物化性质

• 密度：
  1.336±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  98
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-(2-氨基-4-甲基苯氧基)丙烷-1-磺酸 在 盐酸 、 sodium nitrite 、 sodium carbonate 作用下， 以 水 为溶剂， 反应 3.0h， 生成 2-[[4-Amino-2-methyl-5-(3-sulfopropoxy)phenyl]diazenyl]-5-nitrobenzenesulfonic acid
  参考文献：
  名称：

  AZO COMPOUND, INK COMPOSITION AND COLORING MATERIAL

  摘要：

  公开号：

  EP1810999B1

文献信息

• アゾ化合物、インク組成物、記録方法及び着色体
  申请人：日本化薬株式会社

  公开号：JP2016172816A

  公开（公告）日：2016-09-29

  【課題】インクジェット専用紙に記録した場合に、極めて耐(オゾン)ガスに優れ、印字濃度が非常に高く、演色性が少なく、且つ彩度が低く、高品位な黒色の色相を有する色素、及び該色素を含有するインク組成物の提供。【解決手段】式（１）で表されるアゾ化合物或いはその互変異性体、又はそれらの塩。［Ｒ1は（Ｃ１〜Ｃ４）アルキル基等；Ｒ2はシアノ基；Ｒ3及びＲ4は独立にＨ、スルホ基等；Ｒ5及びＲ7は独立に(Ｃ1〜Ｃ4)アルキルチオ基等；Ｒ6及びＲ8は独立にアセチルアミノ基；Ｒ9はスルホ（Ｃ１〜Ｃ４）アルコキシ基；Ｒ10はメチル基；Ｒ11〜Ｒ13は少なくとも１つがシアノ基］【選択図】なし

  如果您需要将文本翻译成中文，这段文字的含义是：提供一种具有极佳耐臭氧气体性能、印刷浓度非常高、色彩稳定性高、饱和度低、且具有高品质黑色色调的染料，以及含有该染料的墨水组成物。解决方案是提供由式（1）表示的偶氮化合物或其互变异构体，或它们的盐。【其中，R1为（C1-C4）烷基等；R2为氰基；R3和R4分别为H、磺酰基等；R5和R7分别为（C1-C4）烷基硫基等；R6和R8分别为乙酰氨基；R9为磺酰（C1-C4）烷氧基；R10为甲基；R11-R13中至少一个为氰基】。
• AZO COMPOUND, INK COMPOSITION, INK JET RECORDING METHOD, AND COLORED ARTICLE
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：US20180319988A1

  公开（公告）日：2018-11-08

  An azo compound and an ink composition containing the azo compound are used as inks for ink jet recording and have excellent gas (ozone) resistance when recording is done on special ink jet paper. The azo compound is represented by formula (1) or a tautomer thereof, or a salt of these. In formula (1), R 1 represents a C1-C4 alkyl group, R 2 represents a cyano group, R 3 and R 4 each independently represent a C1-C4 alkoxy, R 5 -R 10 each independently represent a group represented by formula (2), and R 11 -R 13 each independently represent a nitro group. In formula (2), R 14 is an anilino group, and R 15 is a mono- or di-C1-C6 alkylamino group

  一种偶氮化合物和含有该偶氮化合物的墨水组成物可用作喷墨记录的墨水，在特殊的喷墨纸上进行记录时具有优异的气体（臭氧）抗性。该偶氮化合物由式（1）或其互变异构体或其盐所表示。在式（1）中，R1表示C1-C4烷基，R2表示氰基，R3和R4各自独立地表示C1-C4烷氧基，R5-R10各自独立地表示由式（2）表示的基团，R11-R13各自独立地表示硝基。在式（2）中，R14是苯胺基，R15是单个或双个C1-C6烷基胺基。
• Azo Compound Or Salt Thereof, And Polarizing Film Containing Same
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：US20190048194A1

  公开（公告）日：2019-02-14

  The purpose of the present invention is to provide: a high performance dye-based polarizing film and dye-based polarizing plate, in particular a neutral gray high performance dye-based film and dye-based polarizing plate, having excellent polarizing performance and moisture resistance, heat resistance and light resistance; and an azo compound or a salt thereof able to produce same. The present invention provides an azo compound represented by formula (1) or a salt thereof.

  本发明的目的是提供一种高性能的染料型偏光膜和染料型偏光板，特别是一种中性灰色高性能染料型膜和染料型偏光板，具有优异的偏光性能和耐湿性、耐热性和耐光性；以及能够产生同样效果的偶氮化合物或其盐。本发明提供了由式（1）表示的偶氮化合物或其盐。
• AZO COMPOUND, INK COMPOSITION, RECORDING METHOD AND COLORED MATTER
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP1889882A1

  公开（公告）日：2008-02-20

  The present invention relates to an azo compound represented by the following formula (1) [KA 1] (wherein, each of R1 and R2 independently represents a hydrogen atom, a halogen atom, a cyano group, a carboxyl group, a sulfo group, a sulfamoyl group or the like, each of m and n independently represents 0 or 1, X represents a sulfo group, B represents a substituted p-phenylene group or a substituted p-naphthylene group (these may be substituted by a group selected from the group consisting of a sulfo group, a sulfo C1 to C4 alkoxy group, a C1 to C4 alkyl group and the like), and C represents a substituted phenyl group or a naphthyl group) or a salt thereof, an ink composition containing it, especially a black ink composition. Said pentakis-azo compound is excellent in solubility to medium whose main component is water and suitable for an water-soluble composition (ink composition and the like) for inkjet recording and writing tools; recorded articles recorded using said composition are excellent in fastnesses such as light fastness and ozone gas fastness; bronzing is not generated on the recorded images; and its recording liquids are good in storage stability.

  本发明涉及一种偶氮化合物，由以下式（1）[KA1]表示（其中，R1和R2各自独立地表示氢原子，卤素原子，氰基，羧基，磺酰基，磺酰胺基或类似物，m和n各自独立地表示0或1，X表示磺酰基，B表示取代的对苯撑基或取代的对萘撑基（这些可以被从磺酰基，磺酰C1到C4烷氧基，C1到C4烷基等组成的群体中选择的群体取代），C表示取代的苯基或萘基）或其盐，以及包含它的墨水组成物，特别是黑色墨水组成物。所述五聚偶氮化合物在主要成分为水的介质中具有良好的溶解性，并适用于水溶性组合物（墨水组成物等）用于喷墨记录和书写工具;使用该组成物记录的文章在光牢度和臭氧气体牢度等方面具有优异性;记录图像上不会产生青铜色;其记录液在储存稳定性方面表现良好。
• WATER-SOLUBLE AZO COMPOUNDS, INK COMPOSITIONS AND COLORED PRODUCTS
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP1921116A1

  公开（公告）日：2008-05-14

  The present invention relates to a water-soluble azo compound represented by the following formula (1) [KA 1] (wherein, A represents a hydroxyl group, a morpholino group, an amino group, an aliphatic amine residue which may have a substituent, aromatic amine residue which may have a substituent, a phenoxy group which may have a substituent or an alkoxy group which may have a substituent, R1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R2 represents a substituent selected from a hydrogen atom, a halogen atom, a nitro group and a hydroxyl group, n represents an integer number of 1 to 3, respectively) as free acid and an ink composition comprising the same. Said azo compound has hue having high vividness suitable for inkjet recording, said ink composition is excellent in storage stability, and an inkjet recorded article by using this is excellent in fastnesses such as moisture fastness, ozone gas fastness and light fastness.

  本发明涉及一种由下式（1）表示的水溶性偶氮化合物 [KA 1］ (其中，A 代表羟基、吗啉基、氨基、可有取代基的脂肪胺残基、可有取代基的芳香胺残基、可有取代基的苯氧基或可有取代基的烷氧基、R1 代表氢原子或具有 1 至 4 个碳原子的烷基，R2 代表分别选自氢原子、卤素原子、硝基和羟基的取代基，n 代表 1 至 3 的整数）作为游离酸和包含游离酸的油墨组合物。所述偶氮化合物具有适合喷墨记录的高鲜艳度色调，所述墨水组合物具有优异的储存稳定性，使用该墨水组合物的喷墨记录物品具有优异的耐湿度、耐臭氧气体和耐光性。