5-Methyl-2-(2,4,6-trimethylphenyl)imidazo[1,5-a]pyridinium | 849797-80-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 5-Methyl-2-(2,4,6-trimethylphenyl)imidazo[1,5-a]pyridinium
• 英文别名: 5-methyl-2-(2,4,6-trimethylphenyl)imidazo[1,5-a]pyridin-2-ium
• CAS: 849797-80-4
• 化学式: C17H19N2+
• 分子量: 251.35
• InChiKey: OFTYWHDNJVHNDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  8.3
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• HYDROSILYLATION IRON CATALYST
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20170260216A1

  公开（公告）日：2017-09-14

  A hydrosilylation iron catalyst prepared from a two-electron ligand (L) and a mononuclear, binuclear, or trinuclear complex of iron indicated by formula (1), Fe having bonds with carbon atoms included in X and the total number of Fe-carbon bonds being 2-10. As a result of using iron, the hydrosilylation iron catalyst is advantageous from a cost perspective as well as being easily synthesized. Hydrosilylation reactions can be promoted under mild conditions by using this catalyst. Fe(X) a (1) (in the formula, each X independently indicates a C2-30 ligand that may include an unsaturated group excluding carbonyl groups (CO groups) and cyclopentadienyl groups, however at least one X includes an unsaturated group, a indicates an integer of 2-4 per Fe atom.)

  使用双电子配体（L）和由公式（1）表示的铁的单核、双核或三核配合物制备的水硅化铁催化剂，其中Fe与X中包含的碳原子形成键，Fe-碳键的总数为2-10。由于使用铁，水硅化铁催化剂从成本角度来看具有优势，同时也易于合成。通过使用这种催化剂，可以在温和条件下促进水硅化反应。在公式中，每个X独立地表示一个可能包括除羰基（CO基团）和环戊二烯基团以外的不饱和基团的C2-30配体，然而至少有一个X包括不饱和基团，a表示每个铁原子2-4的整数。）
• HYDROSILYLATION REACTION CATALYST
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20170260215A1

  公开（公告）日：2017-09-14

  A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc.; and a ligand comprising a carbine compound such as 1,3-dimesitylimidazol-2-ylidene, etc. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.

  一种水硅烷基化反应催化剂的制备方法：包括过渡金属化合物的催化剂前体，不包括铂，属于周期表8-10族的过渡金属，例如，醋酸铁、醋酸钴、醋酸镍等；以及包括碳氢化合物的配体，例如1,3-二间苯基咪唑-2-基亚胺等。该水硅烷基化反应催化剂具有优异的搅拌和储存性能。使用该催化剂可以在温和条件下促进水硅烷基化反应。
• Method for treating neurological disorders with imidazolium and imidazolinium compounds
  申请人：Agency for Science, Technology and Research

  公开号：EP2803356A1

  公开（公告）日：2014-11-19

  There is presently provided methods for delivering a neuroprotective agent to a neural cell. The methods comprise contacting a neural cell with an imidazolium or imidazolinium compound as described herein, including an imidazolium or imidazolinium salt.

  目前提供了向神经细胞递送神经保护剂的方法。这些方法包括将神经细胞与本文所述的咪唑或咪唑啉化合物（包括咪唑盐或咪唑啉盐）接触。
• Hydrosilylation reaction catalyst
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10000515B2

  公开（公告）日：2018-06-19

  A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc.; and a ligand comprising a carbine compound such as 1,3-dimesitylimidazol-2-ylidene, etc.. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.

  一种加氢硅烷化反应催化剂，由以下物质制备而成：催化剂前体，包括属于元素周期表第 8-10 族的过渡金属化合物（铂除外），如醋酸铁、醋酸钴、醋酸镍等；配体，包括碳化合物，如 1,3-二甲基咪唑-2-亚基等。这种氢硅烷化反应催化剂具有极佳的处理和储存性能。使用这种催化剂，可以在温和的条件下促进水硅烷化反应。
• METHOD FOR TREATING NEUROLOGICAL DISORDERS WITH IMIDAZOLIUM AND IMIDAZOLINIUM COMPOUNDS
  申请人：Zhuo Lang

  公开号：US20110028513A1

  公开（公告）日：2011-02-03

  There is presently provided methods for delivering a neuroprotective agent to a neural cell. The methods comprise contacting a neural cell with an imidazolium or imidazolinium compound as described herein, including an imidazolium or imidazolinium salt.