Octanitrocubane | 99393-63-2

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: Octanitrocubane
• 英文别名: ONC；1,2,3,4,5,6,7,8-octanitrocubane
• CAS: 99393-63-2
• 化学式: C₈N₈O₁₆
• 分子量: 464.132
• InChiKey: URIPDZQYLPQBMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.6
• 重原子数：
  32
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  367
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  Heptanitrocubane 在 lithium hexamethyldisilazane 、 亚硝酰氯 、 臭氧 作用下， 以 二氯甲烷 为溶剂， 以55%的产率得到Octanitrocubane
  参考文献：
  名称：

  Hepta- and Octanitrocubanes

  摘要：

  Four of the eight nitro groups of octanitrocubane 1 are introduced by functional group modification, three more by the astonishingly rapid, low-temperature N(2)O(4) nitration of sequentially formed polynitrocubyl anions, and the eighth and last by nitrosation of the heptanitrocubyl anion followed by ozonation.

  DOI：

  10.1002/(sici)1521-3773(20000117)39:2<401::aid-anie401>3.0.co;2-p

文献信息

• 3,3'-DINITRO-5,5'-BISTRIAZOLE-1'-DIOL
  申请人：LUDWIG-MAXIMILIANS-UNIVERSITÄT MÜNCHEN

  公开号：US20160024029A1

  公开（公告）日：2016-01-28

  The invention relates to 3,3′-dinitro-5,5′-bis-triazole-1,1′-diol and to salts thereof, and to an energetic active mass comprising said salts.

  这项发明涉及3,3'-二硝基-5,5'-双三唑-1,1'-二醇及其盐，以及包含该盐的活性炸药物质。
• METHOD FOR SYNTHESIS OF TKX-50 USING INSENSITIVE INTERMEDIATE
  申请人：AGENCY FOR DEFENSE DEVELOPMENT

  公开号：US20210163428A1

  公开（公告）日：2021-06-03

  The present invention relates to a method for synthesis of TKX-50 using an insensitive intermediate and, more specifically, to a method for producing TKX-50, the method comprising the steps of: preparing DCG as a starting material; forming a THP-DAG intermediate from the DCG; and synthesizing TKX-50 through the THP-DAG intermediate.

  本发明涉及使用不敏感的中间体合成TKX-50的方法，更具体地，涉及一种生产TKX-50的方法，包括以下步骤：准备DCG作为起始材料；从DCG形成THP-DAG中间体；通过THP-DAG中间体合成TKX-50。
• New synthesis of 2,6-diamino-3,5-dinitropyrazine-1-oxide from 2,6-diaminopyrazine-1-oxide
  申请人：Pagoria Philip F.

  公开号：US20090299067A1

  公开（公告）日：2009-12-03

  A method for the synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide including nitration of 2,6-diaminopyrazine-1-oxide. The step of nitration may use nitrating agents 20% Oleum/100% HNO3, 100% HNO3 and conc. H2504/100% HNO3 or nitronium tetrfluoraoborate. The synthesis of 2,6-diaminopyrazine-1-oxide may involve both the oxidation of 2,6-diaminopyrazine, the amination of a precursor 2,6-disubstitutedpyrazine-1-oxide or direct formation of the 2,6-diaminopyrazine-l-oxide from the precursor, 2-amino-6-hydroxamino-pyrazine-1-oxide.

  一种合成2,6-二氨基-3,5-二硝基吡嗪-1-氧化物的方法，包括对2,6-二氨基吡嗪-1-氧化物进行硝化。硝化步骤可使用硝化剂20％油酸/100％硝酸，100％硝酸和浓H2504/100％硝酸或硝基四氟硼酸盐。2,6-二氨基吡嗪-1-氧化物的合成可以涉及2,6-二氨基吡嗪的氧化、前体2,6-二取代吡嗪-1-氧化物的氨基化或直接从前体2-氨基-6-羟肟基吡嗪-1-氧化物形成2,6-二氨基吡嗪-1-氧化物。
• ENERGETIC ACTIVE COMPOSITION COMPRISING A DIHYDROXYLAMMONIUM SALT OR DIAMMONIUM SALT OF A BISTETRAZOLEDIOL
  申请人：Klapötke Thomas M.

  公开号：US20140171657A1

  公开（公告）日：2014-06-19

  The invention relates to an energetic active composition comprising a dihydroxylammonium salt or diammonium salt of 5,5′-bistetrazole-1,1′-diol, 5,5′-bistetrazole-1,2′-diol or 5,5′-bistetrazole-2,2′-diol or a mixture of at least two of these salts.

  本发明涉及一种含有5,5'-双四唑-1,1'-二醇、5,5'-双四唑-1,2'-二醇或5,5'-双四唑-2,2'-二醇的二羟胺盐或双胺盐，或至少两种这些盐的混合物的活性能量组合物。
• ENERGETIC COCRYSTALS FOR TREATMENT OF A SUBTERRANEAN FORMATION
  申请人：HALLIBURTON ENERGY SERVICES, INC.

  公开号：US20160177698A1

  公开（公告）日：2016-06-23

  The present invention relates to energetic cocrystals, and to methods for using the same for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation, the method including obtaining or providing a composition including energetic cocrystals. Each energetic cocrystal independently includes an energetic compound and a secondary material. The method also includes placing the composition in a subterranean formation.

  本发明涉及具有能量共晶体的相关技术，以及使用这些技术治疗地下地层的方法。在各种实施例中，本发明提供了一种治疗地下地层的方法，该方法包括获得或提供包括能量共晶体的组合物。每个能量共晶体独立地包括一个能量化合物和一个辅助材料。该方法还包括将该组合物放置在地下地层中。