1-(prop-2-ynyloxy)-3-vinylbenzene | 1428947-56-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(prop-2-ynyloxy)-3-vinylbenzene
• 英文别名: 1-Ethenyl-3-prop-2-ynoxybenzene；1-ethenyl-3-prop-2-ynoxybenzene
• CAS: 1428947-56-1
• 化学式: C₁₁H₁₀O
• 分子量: 158.2
• InChiKey: KCUJPARJUFRDQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(prop-2-ynyloxy)-3-vinylbenzene 、 silver nitrate 在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以93%的产率得到(3-(3-vinylphenoxy)prop-1-yn-1-yl)silver
  参考文献：
  名称：

  Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring

  摘要：

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.082
• 作为产物：
  描述：

  3-丙炔-2-氧基苯甲醛 在 potassium tert-butylate 、 甲基三苯基碘化膦 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到1-(prop-2-ynyloxy)-3-vinylbenzene
  参考文献：
  名称：

  Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring

  摘要：

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.082

文献信息

• Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring
  作者：Sam C.K. Hau、Ping-Shing Cheng、Thomas C.W. Mak

  DOI：10.1016/j.poly.2012.06.082

  日期：2013.3

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.