甲基丙烯酸甲酯-丙烯腈-苯乙烯共聚物(MAS-711) | 25213-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 甲基丙烯酸甲酯-丙烯腈-苯乙烯共聚物(MAS-711)
• 中文别名: 甲基丙烯酸甲酯、丙烯腈、苯乙烯的共聚物
• 英文名称: Methyl 2-methylprop-2-enoate;prop-2-enenitrile;styrene
• CAS: 25213-88-1
• 化学式: C16H19NO2
• 分子量: 257.33
• InChiKey: DEAKWVKQKRNPHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.76
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  3

制备方法与用途

用途：

• 用于制笔、牙刷柄、汽车零部件、仪器仪表的壳体和部件等。

反应信息

• 作为产物：
  描述：

  甲基丙烯酸甲酯 、 丙烯腈 、 苯乙烯 、 以to obtain methylmethacrylate-acrylonitrile-styrene copolymer resin (MSAN) with a weight average molecular weight of about 105,000 in bead form的产率得到甲基丙烯酸甲酯-丙烯腈-苯乙烯共聚物(MAS-711)
  参考文献：
  名称：

  Optical Disc Using Methylmethacrylate-Acrylonitrile-Butadiene-Styrene Copolymer Resin

  摘要：

  一张光盘包括一个记录信息的活动盘和一个用于保护活动盘的虚拟盘。活动盘和虚拟盘被粘合成一个单体，虚拟盘由甲基丙烯酸甲酯-丙烯腈-丁二烯-苯乙烯共聚物（MABS）树脂制成。

  公开号：

  US20070224384A1

文献信息

• Resin composition for direct vapor deposition, molded articles made by using the same, and surface-metallized lamp housing
  申请人：——

  公开号：US20040249069A1

  公开（公告）日：2004-12-09

  The direct vapor depositing resin composition of the present invention comprises at least one selected from the group consisting of (A-I): a graft copolymer obtained by graft-polymerizing one or more monomers or a monomer mixture to a complex rubber-like polymer (G) composed of a polyorganosiloxane and a (meth)acrylate-based polymer and (A-II): a graft copolymer obtained by graft-polymerizing one or more monomers or a monomer mixture including an alkyl(meth)acrylate as an essential component to a rubber-like polymer (R) in which the content of diene units is 30% by weight or less in 100% by weight of the whole rubber-like polymer. The direct vapor depositing resin composition of the present invention can provide a beautiful bright appearance after direct vapor deposition of a metal, further, has high level mechanical strengths such as impact strength and the like, and weather resistance, and is also excellent in hot plate welding property with a transparent resin such as PMMA resins, PC resins and the like.

  本发明的直接气相沉积树脂组合物包括至少从(A-I)组中选择的一个：通过将一个或多个单体或单体混合物接枝聚合到由聚有机硅氧烷和（甲基）丙烯酸酯基聚合物组成的复合橡胶状聚合物（G）中得到的接枝共聚物；或通过将一个或多个单体或单体混合物（包括烷基（甲基）丙烯酸酯作为必要组分）接枝聚合到橡胶状聚合物（R）中得到的接枝共聚物，其中二烯单元的含量在整个橡胶状聚合物的100%重量中为30%重量以下。本发明的直接气相沉积树脂组合物可以在直接气相沉积金属后提供美丽明亮的外观，而且具有高水平的机械强度，如冲击强度等，耐候性，并且在与PMMA树脂、PC树脂等透明树脂进行热板焊接时也具有优异的性能。
• RESIN COMPOSITION FOR DIRECT VAPOR DEPOSITION, MOLDED ARTICLES MADE BY USING THE SAME, AND SURFACE-METALLIZED LAMP HOUSING
  申请人：NAKAI Yoshihiro

  公开号：US20100159134A1

  公开（公告）日：2010-06-24

  The direct vapor depositing resin composition of the present invention comprises at least one selected from the group consisting of (A-I): a graft copolymer obtained by graft-polymerizing one or more monomers or a monomer mixture to a complex rubber-like polymer (G) composed of a polyorganosiloxane and a (meth)acrylate-based polymer and (A-II): a graft copolymer obtained by graft-polymerizing one or more monomers or a monomer mixture including an alkyl (meth)acrylate as an essential component to a rubber-like polymer (R) in which the content of diene units is 30% by weight or less in 100% by weight of the whole rubber-like polymer. The direct vapor depositing resin composition of the present invention can provide a beautiful bright appearance after direct vapor deposition of a metal, further, has high level mechanical strengths such as impact strength and the like, and weather resistance, and is also excellent in hot plate welding property with a transparent resin such as PMMA resins, PC resins and the like.

  本发明的直接气相沉积树脂组合物包括从（A-I）组中选择的至少一种：通过将一种或多种单体或单体混合物接枝聚合到由聚有机硅氧烷和（甲基）丙烯酸酯基聚合物组成的复合橡胶状聚合物（G）上获得的接枝共聚物，以及（A-II）：通过将一种或多种单体或单体混合物包括烷基（甲基）丙烯酸酯作为必要组分接枝聚合到橡胶状聚合物（R）中，其中二烯单元的含量在整个橡胶状聚合物的100%重量中为30%重量以下的接枝共聚物。本发明的直接气相沉积树脂组合物在金属的直接气相沉积后可以提供美丽的亮丽外观，此外，具有高水平的机械强度，例如冲击强度等，以及耐候性，还具有与PMMA树脂，PC树脂等透明树脂的热板焊接性优异。
• Optical disc using methylmethacrylate-acrylonitrile-butadiene-styrene copolymer resin
  申请人：Cheil Industries Inc.

  公开号：US07833603B2

  公开（公告）日：2010-11-16

  An optical disc includes an active disc on which information is recorded and a dummy disc for protecting the active disc. The active disc and the dummy disc are bonded to form a single body, and the dummy disc is made of methylmethacrylate-acrylonitrile-butadiene-styrene copolymer (MABS) resin.

  一种光盘包括一个记录信息的活动盘和一个用于保护活动盘的虚拟盘。活动盘和虚拟盘被粘合成一个整体，虚拟盘由甲基丙烯酸甲酯-丙烯腈-丁二烯-苯乙烯共聚物（MABS）树脂制成。
• MATERIAL FOR FUSED DEPOSITION MODELING TYPE THREE-DIMENSIONAL MODELING, AND FILAMENT FOR FUSED DEPOSITION MODELING TYPE 3D PRINTING DEVICE
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20160177078A1

  公开（公告）日：2016-06-23

  [Problem] To provide a material for fused-deposition-type three-dimensional modeling whereby a warp-free modeled object is obtained without devising a modeling shape and without installing a special apparatus as a 3D printer device, and whereby a modeled article having flexibility as well as excellent surface polishing properties is obtained. [Solution] A material for fused-deposition-type three-dimensional modeling, obtained by blending 10-900 parts by weight of a styrene-based resin (B1) obtained by copolymerization of an aromatic vinyl-monomer (b1) and a cyanated vinyl-monomer (b2), and/or 5-400 parts by weight of a thermoplastic resin (B2) having a glass transition temperature of 20° C. or lower and/or 5-30 parts by weight of a plasticizer (B3), with respect to 100 parts by weight of a polylactic resin (A).

  [问题] 提供一种用于熔融沉积型三维建模的材料，通过该材料可以获得无翘曲的建模物体，无需设计建模形状，也无需安装特殊设备作为3D打印机设备，同时可以获得具有柔韧性和优异表面抛光性的建模物品。 [解决方案] 通过将10-900重量份的苯乙烯基树脂（B1）与芳香族乙烯单体（b1）和氰基乙烯单体（b2）共聚而得，和/或5-400重量份的玻璃化转变温度低于20℃的热塑性树脂（B2），和/或5-30重量份的增塑剂（B3）与100重量份的聚乳酸树脂（A）混合而得到一种用于熔融沉积型三维建模的材料。
• Thermoplastic compositions containing a vinyl chloride polymer and a thermoplastic binary copolymer
  申请人：ETHYL CORPORATION

  公开号：EP0053080A2

  公开（公告）日：1982-06-02

  A thermoplastic composition made up of an intimate admixture of (a) a vinyl chloride polymer, and (b) a thermoplastic copolymer of a vinyl aromatic compound and an imide derivative of an ethylenically unsaturated dicarboxylic acid. The preferred blends contain from 90 to 40 weight percent of (a) and 10 to 60 weight percent of (b).

  一种热塑性组合物，由(a)氯乙烯聚合物和(b)乙烯基芳香族化合物与乙烯基不饱和二羧酸亚胺衍生物的热塑性共聚物紧密混合而成。优选的混合物中，(a)的重量百分比为 90%至 40%，(b)的重量百分比为 10%至 60%。