4,7-dioxa-5,5,6,6-tetramethyldecane-1,10-diol bis(p-toluenesulfonate) | 150503-13-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,7-dioxa-5,5,6,6-tetramethyldecane-1,10-diol bis(p-toluenesulfonate)
• 英文别名: 4,7-dioxy-5,5,6,6-tetramethyldecane-1,10-diol bis(p-toluenesulfonate)；2,3-bis(3-[p-toluenesulfonyloxy]propoxy)-2,3-dimethylbutane；3-[2,3-Dimethyl-3-[3-(4-methylphenyl)sulfonyloxypropoxy]butan-2-yl]oxypropyl 4-methylbenzenesulfonate
• CAS: 150503-13-2
• 化学式: C₂₆H₃₈O₈S₂
• 分子量: 542.715
• InChiKey: FZOHQPSESNHKNY-UHFFFAOYSA-N

物化性质

• 熔点：
  123-124 °C
• 沸点：
  643.8±55.0 °C(predicted)
• 密度：
  1.187±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  36
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  122
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4,7-dioxa-5,5,6,6-tetramethyldecane-1,10-diol bis(p-toluenesulfonate) 在 palladium on activated charcoal sodium hydroxide 、 三乙醇胺 、 氢气 、 cesium fluoride 作用下， 以 乙醇 、 水 、 溶剂黄146 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 78.17h， 生成 6,6,7,7-tetramethyl-3,4,6,7,10,11-hexahydro-2H,9H,14H-[1,4,8,11]tetraoxacyclotetradecino[2,3-c]pyrrole
  参考文献：
  名称：

  3,4-Alkylenedioxypyrroles:  Functionalized Derivatives as Monomers for New Electron-Rich Conducting and Electroactive Polymers

  摘要：

  New functionalized derivatives of 3,4-ethylenedioxypyrrole (EDOP, 5a) and 3,4-(1,3-propylenedioxy)-pyrrole (ProDOP, 5b) as especially electron-rich monomers which yield highly electroactive and stable conducting polymers useful for a diverse set Of applications have been synthesized. N-Alkylations of ProDOP were carried out to yield a variety of ProDOP derivatives having alkyl, sulfonatoalkoxy, glyme, and glyme alcohol pendant chains. Iodization of EDOP and ProDOP via iodo-decarboxylation afforded iodo-functionalized derivatives useful for subsequent aryl coupling chemistry. N-Protection and formylation of EDOP, followed by Knoevenagel condensation of the resultant 2-formyl-EDOP with aryl acetonitrile derivatives, led to 1-cyano-2-(2-(3,4-ethylenedioxy-pyrryl))-1-(2-thienyl)vinylene (23) (Th-CNV-EDOP) and 1-cyano-2-(2-(3,4-ethylenedioxypyrryl))-1-(2-(3,4-ethylenedioxythienyl)vinylene (26) (EDOT-CNV-EDOP). A 14-crown-4-ether 34 based dioxypyrrole was synthesized with a cavity potentially useful for lithium ion coordination and sensing in the resultant electroactive polymer. C-Alkylated ProDOPs (43a, 43b, and 43c) containing octyl, ethylhexyl, and dioctyl substituents appended to the central methylene of the propylene bridge, were prepared as monomers for potentially soluble pi -conjugated polymers.

  DOI：

  10.1021/jo001620l
• 作为产物：
  描述：

  2,3-bis(allyloxy)-2,3-dimethylbutane 在 sodium hydroxide 、 sodium tetrahydroborate 、 三氟化硼乙醚 、 双氧水 作用下， 以 吡啶 为溶剂， 反应 4.0h， 生成 4,7-dioxa-5,5,6,6-tetramethyldecane-1,10-diol bis(p-toluenesulfonate)
  参考文献：
  名称：

  Lithium ion selective optical fiber sensor based on a novel neutral ionophore and a lipophilic anionic dye

  摘要：

  DOI：

  10.1021/ac00067a028

文献信息

• Electrochromic polymers and polymer electrochromic devices
  申请人：University of Florida

  公开号：US20030174377A1

  公开（公告）日：2003-09-18

  The subject invention pertains to electrochromic polymers and polymer electrochromic devices. In a specific embodiment, two complementary polymers can be matched and incorporated into dual polymer electrochromic devices. The anodically coloring polymers in accordance with the subject invention can allow control over the color, brightness, and environmental stability of an electrochromic window. In addition, high device contrast ratios, high transmittance changes, and high luminance changes can be achieved, along with half-second switching times for full color change. Also provided are electrochromic devices such as advertising signage, video monitors, stadium scoreboards, computers, announcement boards, warning systems for cell phones, warning/information systems for automobiles, greeting cards, electrochromic windows, billboards, electronic books, and electrical wiring. The subject invention also provides for the use of complementary electrochromic polymers in the manufacture of electrochromic devices. In some embodiments, the devices of the invention can be prepared using metal vapor deposition or line patterning.

  本发明涉及电致变色聚合物和聚合物电致变色器件。在一个特定的实施例中，可以将两种互补的聚合物配对并纳入双聚合物电致变色器件中。根据本发明的阳极着色聚合物可以允许控制电致变色窗户的颜色、亮度和环境稳定性。此外，可以实现高对比度比、高透射率变化和高亮度变化，以及半秒钟的全彩色变换时间。还提供了电致变色器件，例如广告标志、视频监视器、体育场记分牌、计算机、公告牌、手机警告系统、汽车警告/信息系统、贺卡、电致变色窗户、广告牌、电子书和电气布线。本发明还提供了在制造电致变色器件时使用互补电致变色聚合物的方法。在一些实施例中，可以使用金属蒸汽沉积或线路图案制备本发明的器件。
• Design and synthesis of highly selective ionophores for lithium ion based on 14-crown-4 derivatives for an ion-selective electrode
  作者：Koji. Suzuki、Hiroyuki. Yamada、Kazunari. Sato、Kazuhiko. Watanabe、Hideaki. Hisamoto、Yoshito. Tobe、Kazuya. Kobiro

  DOI：10.1021/ac00071a012

  日期：1993.12.1

  Highly Li+-selective ionophores based on 14-crown-4 derivatives were designed and synthesized, and the relationship of their molecular structures and ion selectivities was investigated in order to obtain a highly Li+-selective electrode. The ion selectivities were examined with 11 kinds of 14-crown-4 derivatives, which were prepared according to the proposed two types of Li+ ionophore models. Excellent Li+-selective ionophores were obtained by introducing a bulky ''block'' subunit into the ethano-bridge section of the base crown ring, which effectively prevents the formation of a 2:1 or 3:1 sandwich-type complex consisting of the crown ether and cations larger than Li+. The best Li+/Na+ selectivity (more than 1000) was obtained for the electrode using the 14-crown-4 derivative with a bulky decalin subunit. These results offer the general ion selectivity features of 14-crown-4-based compounds.
• ELECTROCHROMIC POLYMERS AND POLYMER ELECTROCHROMIC DEVICES
  申请人：University of Florida

  公开号：EP1465962A1

  公开（公告）日：2004-10-13
• US6791738B2
  申请人：——

  公开号：US6791738B2

  公开（公告）日：2004-09-14
• [EN] ELECTROCHROMIC POLYMERS AND POLYMER ELECTROCHROMIC DEVICES<br/>[FR] POLYMERES ELECTROCHROMIQUES ET DISPOSITIFS ELECTROCHROMIQUES POLYMERIQUES
  申请人：UNIV FLORIDA

  公开号：WO2003046106A1

  公开（公告）日：2003-06-05

  The subject invention pertains to electrochromic polymers and polymer electrochromic devices. In a specific embodiment, two complementary polymers can be matched and incorporated into dual polymer electrochromic devices. The anodically coloring polymers in accordance with the subject invention can allow control over the color, brightness, and environmental stability of an electrochromic window. In addition, high device contrast ratios, high transmittance changes, and high luminance changes can be achieved, along with half-second switching times for full color change. Also provided are electrochromic devices such as advertising signage, video monitors, stadium scoreboards, computers, announcement boards, warning systems for cell phones, warning/information systems for automobiles, greeting cards, electrochromic windows, billboards, electronic books, and electrical wiring. The subject invention also provides for the use of complementary electrochromic polymers in the manufacture of electrochromic devices. In some embodiments, the devices of the invention can be prepared using metal vapor deposition or line patterning.