[3,5-Bis(methoxymethoxymethyl)phenyl] trifluoromethanesulfonate | 383175-92-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [3,5-Bis(methoxymethoxymethyl)phenyl] trifluoromethanesulfonate
• 英文别名: [3,5-bis(methoxymethoxymethyl)phenyl] trifluoromethanesulfonate
• CAS: 383175-92-6
• 化学式: C₁₃H₁₇F₃O₇S
• 分子量: 374.335
• InChiKey: VUBGTZMNOREONU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  88.7
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  [3,5-Bis(methoxymethoxymethyl)phenyl] trifluoromethanesulfonate 、 5-trimethylsilylbenzene-1,3-diboronic acid dipinacol ester 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 potassium phosphate 作用下， 以 1,4-二氧六环 、 二氯甲烷 为溶剂， 反应 48.0h， 以64%的产率得到[3,5-Bis[3,5-bis(methoxymethoxymethyl)phenyl]phenyl]-trimethylsilane
  参考文献：
  名称：

  Synthesis of a chiral micelle-like dendrimer with phenylene dendrons and a 1,1′-binaphthyl core

  摘要：

  A novel chiral micelle-like dendrimer has been synthesized. This dendrimer contains a chiral binaphthyl core, meia-phenylene dendrons, and hydrophilic polyhydroxyl periphery groups. It is soluble in highly polar solvents such H2O;THF, MeOH THF, EtOH THF and DMSO. but insoluble in EtOAc, CH2Cl2 and CHCl3. The Study by UV-vis absorption spectroscopy reveals that the dendrimer may have a tighter conformation in a less polar solvent than in a more polar solvent. This dendrimer shows strong fluorescence in solution. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(01)01569-6
• 作为产物：
  描述：

  5-羟基间苯二甲酸二甲酯 在 吡啶 、 咪唑 、 lithium aluminium tetrahydride 、 四丁基氟化铵 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 0.5h， 生成 [3,5-Bis(methoxymethoxymethyl)phenyl] trifluoromethanesulfonate
  参考文献：
  名称：

  Synthesis of a chiral micelle-like dendrimer with phenylene dendrons and a 1,1′-binaphthyl core

  摘要：

  A novel chiral micelle-like dendrimer has been synthesized. This dendrimer contains a chiral binaphthyl core, meia-phenylene dendrons, and hydrophilic polyhydroxyl periphery groups. It is soluble in highly polar solvents such H2O;THF, MeOH THF, EtOH THF and DMSO. but insoluble in EtOAc, CH2Cl2 and CHCl3. The Study by UV-vis absorption spectroscopy reveals that the dendrimer may have a tighter conformation in a less polar solvent than in a more polar solvent. This dendrimer shows strong fluorescence in solution. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(01)01569-6