Tris<(diphenylphosphanyl)methyl>methan | 155850-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tris<(diphenylphosphanyl)methyl>methan
• 英文别名: 1,1,1-tris-((diphenylphosphanyl)methyl)methane；1,1,1-tris(diphenylphosphinomethyl)methane；1,1,1-tris(diphenylphosphinomethyl)ethane；tdppmm；Tris[(diphenylphosphanyl)methyl]methan；[3-Diphenylphosphanyl-2-(diphenylphosphanylmethyl)propyl]-diphenylphosphane
• CAS: 155850-41-2
• 化学式: C₄₀H₃₇P₃
• 分子量: 610.655
• InChiKey: CFYZYTMLFDEFRD-UHFFFAOYSA-N

物化性质

• 沸点：
  704.6±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  43
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tris(2-bromo-5-azidobenzyl)amine 、 Tris<(diphenylphosphanyl)methyl>methan 以 乙醚 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  调制所述螺旋桨状的一个三角架C（CH的形状2 PPH 2）3通过取代基的大小在macrobicyclic枢碳原子片段三λ 5 -phosphazenes

  摘要：

  手性macrobicyclic三λ 5个由三球三角架三（3-叠氮基苄）胺和1,1,1-三耦合形成-phosphazenes [（二苯基膦基）甲基]甲烷本螺旋拓扑作为将两个螺旋桨形的结果三脚架碎片具有相同的扭曲感。在低级叔丁烷片段R piv –C（CH 2 PPh 2）3的枢轴碳处引入一系列尺寸逐渐增加的R piv取代基，导致下部螺旋桨的螺旋度逐渐降低。这种现象被揭示在他们的CDCL 3溶液的NMR谱，和活化能为三λ的外消旋化过程5-磷腈通过聚结VT-NMR实验计算。

  DOI：

  10.1016/j.tet.2007.03.076
• 作为产物：
  描述：

  2-羟甲基-1,3-丙二醇 、 二苯基膦 在 吡啶 、 氯化亚砜 、 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 22.0h， 以42%的产率得到Tris<(diphenylphosphanyl)methyl>methan
  参考文献：
  名称：

  Center-to-propeller and propeller-to-propeller stereocontrol in a series of macrobicyclic tri-λ5-phosphazenes

  摘要：

  Center-to-propeller stereocontrol in a family of macrobicyclic, double-propeller shaped tri-lambda(5)-triphosphazenes remains constant in the upper tribenzylamine fragment as the size of the pivotal group at the lower tris(phosphane) fragment is gradually increased. In contrast the propeller-to-propeller stereocontrol diminishes as a result of the increasing conformational lability in the lower hemisphere. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.03.087

文献信息

• Ring slippage in indenyl derivatives of molybdenum and tungsten
  作者：JoséR. Ascenso、Isabel S. Gonçalves、Eberhardt Herdtweck、Carlos C. Romão

  DOI：10.1016/0022-328x(95)05859-n

  日期：1996.2

  Ring slippage of the indenyl occurs upon dissolution of the complexes [η5-IndM(CO)2L2]BF4 (M=Mo of W; L=NCMe or dimethylformamide) in an excess of L, to give [(η3-Ind)M(CO)2L3]Bf4. Other ring-slipped complexes synthesized are [(η3-Ind)Mo(CO)2L3]BF4 (L3=HC(pz)3, [HB(pz)3]−, Me3tacn or en(NCMe)}). Addition of NCMe or an excess of L failed to give ring slippage in [η5-IndMo(CO)2L2]BF4 (L2=bipy, dppe

  茚基的环滑动时发生的复合物的溶解[ η 5 -IndM（CO）2大号2 ] BF 4（W的M =钼; L = NCMe或二甲基甲酰胺）在过量的升，得到[（η 3 -Ind）M（CO）2 L 3 ] Bf 4。其他环滑落合成络合物[（η 3 -Ind）的Mo（CO）2大号3 ] BF 4（L 3 = HC（PZ）3，[HB（PZ）3 ] -中，Me 3 TACN或EN（ NCMe）}）。添加NCMe或过量的L未能在[η 5 -IndMo（CO）2大号2 ] BF 4（L 2 =联吡啶，DPPE，（PME 3）2，P（OME）3 } 2或三磷酸）。NMR和X射线研究揭示了大量折叠的η 3 -茚基环。
• [EN] PROCESS FOR THE PRODUCTION OF ACETALS FROM CARBON DIOXIDE<br/>[FR] PROCÉDÉ DE PRODUCTION D'ACÉTALS À PARTIR DE DIOXYDE DE CARBONE
  申请人：BASF SE

  公开号：WO2020161175A1

  公开（公告）日：2020-08-13

  The invention relates to a process for the preparation of acetals from carbon dioxide. The invention also relates to a mixture of phosphorus containing ligands comprising least one polydentate ligand and at least one monodentate ligand. Further, the invention also relates to the use of mixtures comprising at least one polydentate ligand and at least one monodentate ligand in transition metal complexes for the preparation of acetals.

  该发明涉及一种从二氧化碳制备缩醛的方法。该发明还涉及一种含磷配体混合物，包括至少一种多牙配体和至少一种单牙配体。此外，该发明还涉及在过渡金属配合物中使用至少一种多牙配体和至少一种单牙配体的混合物以制备缩醛。
• Modulating the propeller-like shape of a tripodal C(CH2PPh2)3 fragment by the size of the substituent at the pivotal carbon atom in macrobicyclic tri-λ5-phosphazenes
  作者：Mateo Alajarín、Carmen López-Leonardo、José Berná

  DOI：10.1016/j.tet.2007.03.076

  日期：2007.5

  The chiral macrobicyclic tri-λ5-phosphazenes formed by tripod–tripod coupling of tris(3-azidobenzyl)amines and 1,1,1-tris[(diphenylphosphino)methyl]methanes present helical topologies as a result of combining two propeller-shaped tripodal fragments with the same sense of twist. The introduction of a series of Rpiv substituents of increasing size at the pivotal carbon of the lower tert-butane fragment

  手性macrobicyclic三λ 5个由三球三角架三（3-叠氮基苄）胺和1,1,1-三耦合形成-phosphazenes [（二苯基膦基）甲基]甲烷本螺旋拓扑作为将两个螺旋桨形的结果三脚架碎片具有相同的扭曲感。在低级叔丁烷片段R piv –C（CH 2 PPh 2）3的枢轴碳处引入一系列尺寸逐渐增加的R piv取代基，导致下部螺旋桨的螺旋度逐渐降低。这种现象被揭示在他们的CDCL 3溶液的NMR谱，和活化能为三λ的外消旋化过程5-磷腈通过聚结VT-NMR实验计算。
• Bonding and Activation of N₂in Mo(0) Complexes Supported by Hybrid Tripod Ligands with Mixed Dialkylphosphine/Diarylphosphine Donor Groups: Interplay of Steric and Electronic Factors
  作者：Ludger Söncksen、Christian Gradert、Jan Krahmer、Christian Näther、Felix Tuczek

  DOI：10.1021/ic400582v

  日期：2013.6.3

  Molybdenum dinitrogen complexes are presented which are supported by novel hybrid tripod ligands of the type Me-C(CH2PPh2)2(CH2PiPr2) (trpd-1) and H–C(CH2PPh2)(CH2PiPr2)2 (trpd-2) having mixed dialkylphosphine/diarylphosphine donor groups. Reaction of the ligand trpd-1 with [MoI3(thf)3] followed by sodium amalgam reduction in the presence of the dppm gives the dinitrogen complex [Mo(N2)(trpd-1)(dmpm)]

  提出了二氮钼配合物，这些配合物由新型Me-C（CH 2 PPh 2）2（CH 2 P i Pr 2）（trpd-1）和H-C（CH 2 PPh 2）混合三脚架配体支持CH 2 P我镨2）2（trpd-2具有）混合二烷基膦/二芳基供体基团。配体trpd-1与[MoI 3（thf）3 ]的反应，然后在dppm存在下还原钠汞齐，得到二氮配合物[Mo（N 2）（trpd-1）（DMPM）]其中trpd-1在一个κ协调3方式。该复合物表现出适度的N 2活化，这使得其在保留五膦连接的情况下能够质子化。发现用空间要求更高的大肠菌素dppm代替dmpm会阻碍N 2的配位，并导致[Mo（trpd-1）（dppm）]，这是第一个具有结构特征的仅具有磷化氢的五配位Mo（0）配合物配体球。采用配体trpd-2沿着与二膦DMPM和DPPM以类似的合成路线导致双（二氮）的混合物中复合物的反式[沫（N - 2）2（κ 2-trpd-2）（二膦）]和反式-
• METHOD FOR PRODUCING ALCOHOL BY HYDROGENATING LACTONE AND CARBOXYLIC ACID ESTER IN LIQUID PHASE
  申请人：Maeda Hirofumi

  公开号：US20100113842A1

  公开（公告）日：2010-05-06

  Disclosed is a method for producing an alcohol from a lactone or a carboxylic acid ester, which enables to produce an alcohol from a lactone or a carboxylic acid ester under relatively mild conditions with high yield and high catalytic efficiency. This method also enables to produce an optically active alcohol from an optically active lactone or an optically active carboxylic acid ester. Specifically disclosed is a method for producing an alcohol by hydrogen reducing a lactone or a carboxylic acid ester in the presence of a catalyst containing ruthenium and a phosphine compound represented by the following general formula (1): wherein R 1 represents a spacer; R 2 , R 3 , R 4 , R 5 , R 6 and R 7 independently represent a hydrogen atom, an alkyl group having 1-12 carbon atoms, an aryl group or a heterocyclic group; and R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently represent an alkyl group having 1-12 carbon atoms, an aryl group or a heterocyclic group.

  本发明公开了一种从内酯或羧酸酯中制备醇的方法，该方法可以在相对温和的条件下高收率、高催化效率地从内酯或羧酸酯中制备醇。该方法还可以从手性内酯或手性羧酸酯中制备手性醇。具体公开了一种通过在催化剂中加入钌和以下通式（1）所代表的膦化合物的存在下，氢化还原内酯或羧酸酯制备醇的方法：其中R1代表间隔物，R2、R3、R4、R5、R6和R7分别独立地代表氢原子、具有1-12个碳原子的烷基、芳基或杂环基，R8、R9、R10、R11、R12和R13分别独立地代表具有1-12个碳原子的烷基、芳基或杂环基。