Cyclobut-1-enecarboxylic acid 4-chloro-butyl ester | 1210072-22-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyclobut-1-enecarboxylic acid 4-chloro-butyl ester
• 英文别名: 4-chlorobutyl cyclobutene-1-carboxylate
• CAS: 1210072-22-2
• 化学式: C₉H₁₃ClO₂
• 分子量: 188.654
• InChiKey: BCAMGEBNHZETHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  cyclobutene-1-carbonyl chloride 、 4-氯丁醇 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 16.75h， 以38%的产率得到Cyclobut-1-enecarboxylic acid 4-chloro-butyl ester
  参考文献：
  名称：

  Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers

  摘要：

  Catalysis of alternating ROMP with (H(2)IMes)Cl2Ru=CHPh(OiPr), the second generation Hoveyda Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.

  DOI：

  10.1021/ol101432m

文献信息

• ALTERNATING RING-OPENING METATHESIS POLYMERIZATION
  申请人：Sampson Nicole

  公开号：US20110212046A1

  公开（公告）日：2011-09-01

  The invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. The invention provides regioregular alternating polymers and methods of synthesizing such polymers.

  这项发明涉及聚合物和烯烃聚合领域，更具体地涉及烯烃交换聚合。该发明提供了规则交替聚合物和合成这种聚合物的方法。
• Alternating ring-opening metathesis polymerization
  申请人：Sampson Nicole

  公开号：US08795647B2

  公开（公告）日：2014-08-05

  The invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. The invention provides regioregular alternating polymers and methods of synthesizing such polymers.

  本发明涉及聚合物和烯烃聚合领域，更具体地涉及烯烃交换聚合。本发明提供了规则交替的聚合物和合成这种聚合物的方法。
• US8795647B2
  申请人：——

  公开号：US8795647B2

  公开（公告）日：2014-08-05
• [EN] ALTERNATING RING-OPENING METATHESIS POLYMERIZATION<br/>[FR] POLYMÉRISATION PAR MÉTATHÈSE À OUVERTURE DE CYCLE ALTERNÉE
  申请人：RES FOUNDATION OF THE STATE UN

  公开号：WO2010022284A1

  公开（公告）日：2010-02-25

  The invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. The invention provides regioregular alternating polymers and methods of synthesizing such polymers.
• Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers
  作者：Airong Song、Kathlyn A. Parker、Nicole S. Sampson

  DOI：10.1021/ol101432m

  日期：2010.9.3

  Catalysis of alternating ROMP with (H(2)IMes)Cl2Ru=CHPh(OiPr), the second generation Hoveyda Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.