3-chloro-biphenyl-4,4'-diol | 53905-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-chloro-biphenyl-4,4'-diol
• 英文别名: 3-Chlor-4.4'-dioxy-diphenyl；3-Chlor-biphenyl-4,4'-diol；3-Chloro-4,4'-biphenyldiol；2-Chloro-4-(4-hydroxyphenyl)phenol
• CAS: 53905-34-3
• 化学式: C₁₂H₉ClO₂
• 分子量: 220.655
• InChiKey: KOOMYCULAWPCTA-UHFFFAOYSA-N

物化性质

• 熔点：
  134-136 °C
• 沸点：
  363.4±27.0 °C(Predicted)
• 密度：
  1.349±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (4-溴苯氧基)叔丁基二甲基硅烷 在 四(三苯基膦)钯 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 乙二醇二甲醚 、 水 为溶剂， 反应 0.58h， 生成 3-chloro-biphenyl-4,4'-diol
  参考文献：
  名称：

  ERβ Ligands. Part 1: The discovery of ERβ selective ligands which embrace the 4-hydroxy-biphenyl template

  摘要：

  The synthesis and structure-activity relationships of a series of simple biphenyls is described. Optimization of the 4-hydroxy-biphenyl template led to compounds with ERP selectivity on the order of 20-70-fold. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0968-0896(03)00303-1

文献信息

• POLYMER-(ORGANO)CLAY COMPLEX, COMPOSITION COMPRISING THE COMPLEX, SHEET-LIKE MATERIAL COMPRISING THE COMPLEX OR COMPOSITION, AND METHOD FOR PRODUCTION OF POLYMER-(ORGANO)CLAY COMPLEX
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2113526A1

  公开（公告）日：2009-11-04

  Disclosed are: a high-performance polyphenylene ether-organoclay complex which is significantly improved in fire retardancy, durability (e.g., light resistance, chemical resistance, impact resistance), an ability of being extruded into a sheet and the like; and others. The polyphenylene ether-organoclay complex can be produced by: preparing a mixture comprising a solvent, a catalyst, a phenolic compound and an organoclay, wherein the organoclay is contained in an amount of 0.1 to 20 parts by mass relative to 100 parts by mass of the phenolic compound; contacting the mixture with an oxygen-containing gas to cause the oxidative polymerizationof the phenolic compound; and removing the solvent and the catalyst from the resulting polymerization mixture. This method is applicable to the production of a complex of an organoclay with other polymers such as an aromatic polycarbonate, a polyether imide and a polyacrylate.

  本发明公开了一种高性能聚苯醚-有机土复合物，该复合物在阻燃性、耐久性（如耐光性、耐化学性、耐冲击性）、挤压成片材的能力等方面均有显著改善。聚苯醚-有机土复合物可通过以下方法生产：制备包含溶剂、催化剂、酚类化合物和有机土的混合物，其中有机土的含量相对于 100 份酚类化合物的质量为 0.1 至 20 份；将混合物与含氧气体接触以引起酚类化合物的氧化聚合；以及从生成的聚合混合物中除去溶剂和催化剂。该方法适用于生产有机土与其他聚合物（如芳香族聚碳酸酯、聚醚酰亚胺和聚丙烯酸酯）的复合物。
• Cellulose acylate film, process for producing cellulose acylate film, polarizing plate and liquid crystal display device
  申请人：Fukagawa Nobutaka

  公开号：US20060093759A1

  公开（公告）日：2006-05-04

  A cellulose acylate film that has: an in-plane retardation Re and a retardation Rth in a thickness direction at a wavelength of 590 nm, which are satisfied with ranges of expressions (I) to (III); a coefficient of a thermal expansion of from 20 ppm/° C. to 100 ppm/° C.; and a haze of from 0.01 to 0.8, and a polarizing plate and a display device using the same. 20≦Re≦50  Expression (I) 70≦Rth≦200  Expression (II) 1.0≦Rth/Re≦3.0  Expression (III) In the foregoing expressions, each of Re and Rth is a value at 25° C. and 60% RH, and has a unit of nm.

  一种丙烯酸纤维素薄膜，其在波长为 590 纳米时的面内阻滞率 Re 和厚度方向上的阻滞率 Rth 符合表达式 (I) 至 (III) 的范围；热膨胀系数为 20 ppm/°C 至 100 ppm/°C；雾度为 0.01 至 0.8，以及使用该薄膜的偏光板和显示装置。 20≦Re≦50 Expression (I) 70≦Rth≦200 Expression (II) 1.0≦Rth/Re≦3.0 表达式 (III) 在上述表达式中，Re 和 Rth 均为 25° C 和 60% 相对湿度下的数值，单位为纳米。
• Carbonates of acetylenic alcohols
  申请人：NIPPON PAINT CO., LTD.

  公开号：EP0457334B1

  公开（公告）日：1994-08-10
• II.—Halogen derivatives of diphenyl and dihydroxydiphenyl
  作者：John Cannell Cain

  DOI：10.1039/ct9048500007

  日期：——
• Melt-processable aromatic copolyester
  申请人：Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo

  公开号：EP0212944B1

  公开（公告）日：1992-04-08