3,6-dichloro-3,6-dimethyl-[1,2,4,5]tetroxane | 59183-17-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 3,6-dichloro-3,6-dimethyl-[1,2,4,5]tetroxane
• 英文别名: 1,4-Dimethyl-1,4-dichlor-2,3,5,6-tetroxan；3,6-Dichloro-3,6-dimethyl-1,2,4,5-tetraoxane
• CAS: 59183-17-4
• 化学式: C₄H₆Cl₂O₄
• 分子量: 188.995
• InChiKey: GGRNOSKMVFHOOY-UHFFFAOYSA-N

物化性质

• 沸点：
  270.6°C (rough estimate)
• 密度：
  1.6226 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,6-dichloro-3,6-dimethyl-[1,2,4,5]tetroxane 生成 过氧化乙酰
  参考文献：
  名称：

  GAEB, S.;TURNER, W. V., J. ORG. CHEM., 1984, 49, N 15, 2711-2714

  摘要：

  DOI：
• 作为产物：
  描述：

  (2E)-2,3-二氯-2-丁烯 、 臭氧 生成 3,6-dichloro-3,6-dimethyl-[1,2,4,5]tetroxane
  参考文献：
  名称：

  GAEB, S.;TURNER, W. V., J. ORG. CHEM., 1984, 49, N 15, 2711-2714

  摘要：

  DOI：

文献信息

• THERMOPLASTIC GRAFT COPOLYMER RESIN, METHOD FOR PREPARING SAME, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3290464A1

  公开（公告）日：2018-03-07

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93 % by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.

  本发明涉及一种热塑性接枝共聚物树脂、制备该树脂的方法以及包括该树脂的热塑性树脂组合物。更具体地说，本发明涉及一种热塑性接枝共聚物树脂，包括种子、包覆种子的丙烯酸烷基酯橡胶芯和包覆橡胶芯的外壳、制备方法和包括其在内的热塑性树脂组合物，其中热塑性接枝共聚物树脂的凝胶含量为 93 %（重量）或以上，溶胀指数为 6 至 14。 根据本公开，提供了一种具有优异耐化学性、耐热性和耐冲击性的热塑性接枝共聚物树脂、其制备方法以及包括其在内的热塑性树脂组合物。
• Thermoplastic graft copolymer resin, method of preparing the same, and thermoplastic resin composition including the same
  申请人：LG CHEM, LTD.

  公开号：US10450453B2

  公开（公告）日：2019-10-22

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93% by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.

  本发明涉及一种热塑性接枝共聚物树脂、制备该树脂的方法以及包括该树脂的热塑性树脂组合物。更具体地说，本发明涉及一种热塑性接枝共聚物树脂，包括种子、包覆种子的丙烯酸烷基酯橡胶芯和包覆橡胶芯的外壳、制备方法和包括其在内的热塑性树脂组合物，其中热塑性接枝共聚物树脂的凝胶含量为 93% （重量）或以上，溶胀指数为 6 至 14。根据本公开，提供了一种具有优异耐化学性、耐热性和耐冲击性的热塑性接枝共聚物树脂、其制备方法以及包括其在内的热塑性树脂组合物。
• Nucleophilic Substitution Reactions at Chloro-Substituted Ozonides and at a Chlorinated Dimeric Peroxide
  作者：Karl Griesbaum、Konrad Schlindwein

  DOI：10.1021/jo00129a055

  日期：1995.12

  Reactions of substituted 3-chloro-(2a-4a) and 3,5-dichloro-1,2,4-trioxolanes (9a, 10a) with AgBF4 in the presence of LiF gave the corresponding fluoro-substituted ozonides (2b-4b and 9b and 10b). Substitutions af some of these chlorinated ozonides by the methoxy and by the acetoxy groups, and of 3,6-dichloro-3,6-dimethyl-1,2,4,5-tetrox (22a) with the acetoxy group have been achieved, too.
• Ozonolysis of trans-2,3-dichloro-2-butene. Isolation of .alpha.-chloro peroxides
  作者：Karl Griesbaum、Peter Hofmann

  DOI：10.1021/ja00426a034

  日期：1976.5
• THERMOPLASTIC GRAFT COPOLYMER RESIN, METHOD OF PREPARING THE SAME, AND THERMOPLASTIC RESIN COMPOSITION INCLUDING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20180142094A1

  公开（公告）日：2018-05-24

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93% by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.