3-[(2-氯-4-硝基苯基)偶氮]-9H-咔唑 | 64071-87-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 3-[(2-氯-4-硝基苯基)偶氮]-9H-咔唑
• 英文名称: 3-(2'-chloro-4'-nitrophenylazo)carbazole
• 英文别名: 3-[(2-Chloro-4-nitrophenyl)azo]-9H-carbazole；9H-carbazol-3-yl-(2-chloro-4-nitrophenyl)diazene
• CAS: 64071-87-0
• 化学式: C₁₈H₁₁ClN₄O₂
• 分子量: 350.764
• InChiKey: SZVQEOMBVJZINC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.3
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-[(2-氯-4-硝基苯基)偶氮]-9H-咔唑 、 环氧氯丙烷 在 氢氧化钾 、 四丁基溴化铵 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 6.0h， 以70%的产率得到3-(2'-chloro-4'-nitrophenylazo)-N-(2,3-epoxyprpyl)-carbazole
  参考文献：
  名称：

  Photoinduced Gratings in Functionalized Azo-Carbazole Compounds in Picosecond Regime

  摘要：

  We report results of diffraction grating inscription on thin films prepared from epoxy resin doped with azo-carbazole based dyes. Diffraction gratings were recorded at the wavelength 532 nm and monitored through intensity of first order of diffraction (632 nm). Atomic force microscope scans of the gratings show that a surface relief grating also appeared.

  DOI：

  10.1080/15421400801926396
• 作为产物：
  描述：

  咔唑 、 2-氯-4-硝基苯胺 在 盐酸 、 sodium nitrite 作用下， 以 水 、 正丁醇 为溶剂， 反应 0.5h， 生成 3-[(2-氯-4-硝基苯基)偶氮]-9H-咔唑
  参考文献：
  名称：

  Photoinduced Gratings in Functionalized Azo-Carbazole Compounds in Picosecond Regime

  摘要：

  We report results of diffraction grating inscription on thin films prepared from epoxy resin doped with azo-carbazole based dyes. Diffraction gratings were recorded at the wavelength 532 nm and monitored through intensity of first order of diffraction (632 nm). Atomic force microscope scans of the gratings show that a surface relief grating also appeared.

  DOI：

  10.1080/15421400801926396

文献信息

• Photoinduced Gratings in Functionalized Azo-Carbazole Compounds in Picosecond Regime
  作者：Robert Czaplicki、Sylvie Dabos-Seignon、Ileana Rau、Oksana Krupka*、Bouchta Sahraoui、Jacek Nizioł、Monika Bednarz、Jan Pielichowski、Aurelia Meghea、Mina Bakasse

  DOI：10.1080/15421400801926396

  日期：2008.4.17

  We report results of diffraction grating inscription on thin films prepared from epoxy resin doped with azo-carbazole based dyes. Diffraction gratings were recorded at the wavelength 532 nm and monitored through intensity of first order of diffraction (632 nm). Atomic force microscope scans of the gratings show that a surface relief grating also appeared.