3-乙基-4-[(三甲基硅烷基)乙炔基]苯胺 | 546112-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-乙基-4-[(三甲基硅烷基)乙炔基]苯胺
• 英文名称: 3-ethyl-4-trimethylsilanylethynylphenylamine
• 英文别名: 3-Ethyl-4-[(trimethylsilyl)ethynyl]aniline；3-ethyl-4-(2-trimethylsilylethynyl)aniline
• CAS: 546112-58-7
• 化学式: C₁₃H₁₉NSi
• 分子量: 217.386
• InChiKey: IZMPXJGNBPVJRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.06
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  3-乙基-4-[(三甲基硅烷基)乙炔基]苯胺 在 nitrosonium tetrafluoroborate 、 碘 、 sodium iodide 作用下， 以 乙腈 为溶剂， 反应 0.83h， 以78%的产率得到1-iodo-3-ethyl-4-<(trimethylsilyl)ethynyl>benzene
  参考文献：
  名称：

  Improved and new syntheses of potential molecular electronics devices

  摘要：

  New syntheses of ethyl and nitro substituted oligo(phenylene ethynylene)s (OPEs) have been developed. To further explore whether the presence of nitro functionality in OPEs leads to switching and memory capabilities, new nitro substituted OPEs have been designed and synthesized. An isatogen-based system, a structure that is isomeric to the nitro OPE, has been synthesized. Additionally, pyridine-based and chromium-based compounds have been synthesized. We surmise that redox reactions of these candidates may impart switching capabilities and electrochemical studies are shown. U-shaped OPEs were synthesized to inhibit leakage of metals deposited during formation of top contacts on self-assembled monolayers (SAMs). The OPEs contain either thiol-based moieties or isonitrile groups to enable formation of SAMs on metal substrates. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(03)00246-1
• 作为产物：
  描述：

  间硝基苯乙酮 在 palladium on activated charcoal 盐酸 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 氢气 、 碳酸氢钠 、 三乙胺 、 benzyl triethylammonium dichloroiodate 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 、 二氯甲烷 为溶剂， 70.0 ℃ 、413.68 kPa 条件下， 反应 26.17h， 生成 3-乙基-4-[(三甲基硅烷基)乙炔基]苯胺
  参考文献：
  名称：

  Improved and new syntheses of potential molecular electronics devices

  摘要：

  New syntheses of ethyl and nitro substituted oligo(phenylene ethynylene)s (OPEs) have been developed. To further explore whether the presence of nitro functionality in OPEs leads to switching and memory capabilities, new nitro substituted OPEs have been designed and synthesized. An isatogen-based system, a structure that is isomeric to the nitro OPE, has been synthesized. Additionally, pyridine-based and chromium-based compounds have been synthesized. We surmise that redox reactions of these candidates may impart switching capabilities and electrochemical studies are shown. U-shaped OPEs were synthesized to inhibit leakage of metals deposited during formation of top contacts on self-assembled monolayers (SAMs). The OPEs contain either thiol-based moieties or isonitrile groups to enable formation of SAMs on metal substrates. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(03)00246-1

文献信息

• Improved and new syntheses of potential molecular electronics devices
  作者：David W Price、Shawn M Dirk、Francisco Maya、James M Tour

  DOI：10.1016/s0040-4020(03)00246-1

  日期：2003.3

  New syntheses of ethyl and nitro substituted oligo(phenylene ethynylene)s (OPEs) have been developed. To further explore whether the presence of nitro functionality in OPEs leads to switching and memory capabilities, new nitro substituted OPEs have been designed and synthesized. An isatogen-based system, a structure that is isomeric to the nitro OPE, has been synthesized. Additionally, pyridine-based and chromium-based compounds have been synthesized. We surmise that redox reactions of these candidates may impart switching capabilities and electrochemical studies are shown. U-shaped OPEs were synthesized to inhibit leakage of metals deposited during formation of top contacts on self-assembled monolayers (SAMs). The OPEs contain either thiol-based moieties or isonitrile groups to enable formation of SAMs on metal substrates. (C) 2003 Elsevier Science Ltd. All rights reserved.