Allyl-trimethyl-phosphonium; chloride | 30417-66-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 四烷基鏻化合物
• 英文名称: Allyl-trimethyl-phosphonium; chloride
• 英文别名: Trimethyl(prop-2-en-1-yl)phosphanium chloride；trimethyl(prop-2-enyl)phosphanium;chloride
• CAS: 30417-66-4
• 化学式: C₆H₁₄P*Cl
• 分子量: 152.604
• InChiKey: GOUBBILRZIZFQQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.92
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-氯丙烯 、 三甲基膦 以 乙醚 为溶剂， 生成 Allyl-trimethyl-phosphonium; chloride
  参考文献：
  名称：

  三烷基膦和（η-烯丙基）二羰基-亚硝酰基铁配合物的两性离子加合物：结构和反应活性

  摘要：

  的[Fe（η-C之间的反应3 ħ 5）（CO）2（NO）]和强碱性的膦配体L [PME 3，PET 3，PBU Ñ 3，或P（C 6 H ^ 11）3 ]在有机溶剂（苯或乙醚）给出了两性离子加合物的[Fe（η 2 -CH 2 CHCH 2 PR 3）（CO）2（NO）]。根据红外光谱和核磁共振光谱以及电导率测量结果确定了该结构。讨论了反应性和分解机理。

  DOI：

  10.1039/dt9840000815

文献信息

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