| 1072119-28-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1072119-28-8
• 化学式: C₁₀₁H₁₄₉BrN₄O₃₆Zn
• 分子量: 2140.59
• InChiKey: VFQIDQKLBLLZBP-OLRIKRPMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 在 四(三苯基膦)钯 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 3.0h， 以27%的产率得到
  参考文献：
  名称：

  Prominent Electron Transport Property Observed for Triply Fused Metalloporphyrin Dimer: Directed Columnar Liquid Crystalline Assembly by Amphiphilic Molecular Design

  摘要：

  A triply fused copper porphyrin dimer, when site-specifically modified on its periphery with hydrophobic and hydrophilic wedges (1(C12/TEG)), self-assembles into a columnar liquid crystalline (LC) mesophase over a wide-temperature range from -17 to 99 degrees C but gives rise to an amorphous solid when modified with only hydrophobic (1(C12/C12)) or hydrophilic wedges (1(TEG/TED)). ALC film, of 1(C12/TEG) displays at 16 degrees C a top-class one-dimensional electron mobility (0.27 cm(2)/V.s), as evaluated from its maximum flash-photolysis time-resolved microwave conductivity.

  DOI：

  10.1021/ja8030714
• 作为产物：
  描述：

  在 吡啶 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 反应 1.0h， 以79%的产率得到
  参考文献：
  名称：

  Prominent Electron Transport Property Observed for Triply Fused Metalloporphyrin Dimer: Directed Columnar Liquid Crystalline Assembly by Amphiphilic Molecular Design

  摘要：

  A triply fused copper porphyrin dimer, when site-specifically modified on its periphery with hydrophobic and hydrophilic wedges (1(C12/TEG)), self-assembles into a columnar liquid crystalline (LC) mesophase over a wide-temperature range from -17 to 99 degrees C but gives rise to an amorphous solid when modified with only hydrophobic (1(C12/C12)) or hydrophilic wedges (1(TEG/TED)). ALC film, of 1(C12/TEG) displays at 16 degrees C a top-class one-dimensional electron mobility (0.27 cm(2)/V.s), as evaluated from its maximum flash-photolysis time-resolved microwave conductivity.

  DOI：

  10.1021/ja8030714