trichloro-tris[diphenyl(3-triethoxysilylpropylamido)phosphate]erbium(III) | 793683-13-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trichloro-tris[diphenyl(3-triethoxysilylpropylamido)phosphate]erbium(III)
• 英文别名: N-diphenoxyphosphoryl-3-triethoxysilylpropan-1-amine;trichloroerbium
• CAS: 793683-13-3
• 化学式: C₆₃H₉₆Cl₃ErN₃O₁₈P₃Si₃
• 分子量: 1634.26
• InChiKey: KWBOUDWQMBBIHW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化铒(III) 、 diphenyl-(3-triethoxysilylpropylamido)phosphate 以 乙醚 为溶剂， 生成 trichloro-tris[diphenyl(3-triethoxysilylpropylamido)phosphate]erbium(III)
  参考文献：
  名称：

  The Er and Yb Complexes with Silicon-Containing Phosphates and Fluorine-Containing Phosphine Oxide: Synthesis, Spectra, and Films

  摘要：

  Three new silicon- and fluorine-containing ligands, namely bis(dimethylamido)(3-triethoxysilyipropylamido)phosphate O = P(NMe2)(2)NHCH2CH2CH2-Si(OEt)(3), diphenyl(3-triethoxysilyipropylamido)phosphate O = P(OPh)(2)NHCH2CH2CH2Si(OEt)(3), and tris(3,3,3-trifluoropropyl)phosphine oxide O = P(CH2CH2CF3)(3) are synthesized. The erbium and ytterbium complexes with amine, phosphate, and phosphine oxide li'gands Ln(NH2R)(3)Cl-3, Ln[O = P(NMe2)(2)NHR](3)Cl-3, Ln[O = P(OPh)(2)NHR](3)Cl-3 (R = CH2CH2CH2Si(OEt)(3)), Ln[O = P(OPh)(3)](3)Cl-3, Ln[O = P(CH2CH2CF3)(3)](3)Cl-3 are produced and their electronic absorption spectra and photoluminescence spectra are studied. The silicon-containing compounds form transparent thermostable films on silicate glass or quartz surface.

  DOI：

  10.1023/b:ruco.0000030166.83903.e0