[Mn(III)(N,N'-ethylenebis(3-methoxysalicylideneiminato))(H2O)2]ClO4 | 253120-16-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Mn(III)(N,N'-ethylenebis(3-methoxysalicylideneiminato))(H2O)2]ClO4
• 英文别名: [Mn(N,N'-ethylene-bis(3-methoxysalicylideneiminate))(water)2]ClO4；[Mn(N,N-ethylene-bis(3-methoxysalicylideneiminate))(H2O)2](ClO4)；(Mn(N,N-ethylene-bis(3-methoxysalicylideneiminate)(H2O)2)(ClO4)；[Mn(N,N-ethylenebis(3-methoxysalicylideneiminate)(H2O)2](ClO4)；[Mn((MeO)C6H3(O)CHNCH2)2(H2O)2]ClO4
• CAS: 253120-16-0
• 化学式: C₁₈H₂₂MnN₂O₆*ClO₄
• 分子量: 516.771
• InChiKey: RPAHXCLRYXMRNO-WCLOSASOSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetracyanonickelate(II) 、 [Mn(III)(N,N'-ethylenebis(3-methoxysalicylideneiminato))(H2O)2]ClO4 以 甲醇 、 水 、 乙腈 为溶剂， 以60%的产率得到(Mn(N,N-methylene-bis(3-ethoxysalicylideneiminate)(H2O))2(Ni(CN)4)
  参考文献：
  名称：

  通过氢键相互作用构建的两个氰化桥杂金属一维链配合物：合成，晶体结构和磁性

  摘要：

  两个三核氰化物桥杂金属Ni（II）– Mn（III）络合物{[Mn（L 1）（H 2 O）] 2 [Ni（CN）4 ]} 2H 2 O（1）和{[Mn（L 2）（H 2 O）] 2 [Ni（CN）4 ]}（2）（L 1 = N，N-亚乙基双（3-甲氧基水杨酸亚硝酸盐； L 2 = N，N-亚乙基双（3-乙氧基水杨酸亚硝酸盐） ）是使用[Ni（CN）4 ] 2−获得的以及两个含双室席夫碱配体的锰（III）化合物。X射线衍射表明，两个氰化物桥联的三核配合物通过分子间的OH-H…O氢键相互作用而自互补，该分子间的水配体由一个分子与相邻分子的四个酚氧原子形成，形成超分子一维链结构。对这两种络合物的磁化率的研究表明，相邻的Mn（III）离子之间总体上弱的反铁磁相互作用。

  DOI：

  10.1080/15533174.2011.594842
• 作为产物：
  描述：

  乙二胺 、 sodium perchlorate monohydrate 、 邻香草醛 、 manganese(III) triacetate dihydrate 以 甲醇 为溶剂， 生成 [Mn(III)(N,N'-ethylenebis(3-methoxysalicylideneiminato))(H2O)2]ClO4
  参考文献：
  名称：

  Diaqua[N,N′-bis(5-methoxysalicylidene)ethylenediaminato-κ⁴O,N,N′,O′]manganese(III) perchlorate, aqua[N,N′-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ⁴O,N,N′,O′](methanol-κO)manganese(III) perchlorate and bis[μ-N,N′-bis(3-methoxysalicylidene)ethylenediaminato-κ⁵O,N,N′,O′:O]bis[(methanol-κO)manganese(III)] diperchlorate

  摘要：

  The title compounds, a hydrogen-bonded linear chain, [Mn( C18H18N2O4)(H2O)(2)] ClO4, ( I), a hydrogen-bonded pseudodimer, [ Mn(C16H10Cl4N2O2)(CH4O)(H2O)] ClO4, ( II), and a dimer, [Mn-2(C18H18N2O4)(2)(CH4O)(2)](ClO4)(2), ( III), respectively, have been structurally characterized. The three complexes are completely different in their structural features, despite identical counter-anions and only slight modification of the substituents in the ligands. Complex ( I) affords an elongated octahedral coordination environment, with axial Mn O( water) distances of 2.259 ( 3) and 2.313 ( 3) angstrom, which forms hydrogen-bonded linear chains along the crystallographic c axis. Hydrogen-bonded pseudo-dimeric compound ( II) also affords an elongated octahedral coordination environment, with axial Mn - O(CH3OH)= 2.222 ( 3) angstrom and Mn - O( water) = 2.266 ( 3) angstrom. Dimeric complex ( III) is centrosymmetric and consists of distorted octahedral Mn atoms, with axial Mn O( CH3OH)= 2.242 ( 2) angstrom and Mn - O( phenolate)= 2.348 ( 1) angstrom, connected via bridging O atoms from one of the ligands. The magnetic properties of the three complexes are described.

  DOI：

  10.1107/s0108270105013545

文献信息

• Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties
  作者：Daopeng Zhang、Hailong Wang、Yuting Chen、Zhong-Hai Ni、Laijin Tian、Jianzhuang Jiang

  DOI：10.1021/ic901530p

  日期：2009.12.7

  [Mn(L1)(H2O)]3[Fe(CN)5(1-CH3im)]}ClO4·1.5H2O (1) and [Mn(L2)(H2O)]3[Fe(CN)5(1-CH3im)]}ClO4·3H2O (2); two heptanuclear cage-shaped MIIIMnIII6 (M = Fe, Cr) compounds, [Mn(L2)(H2O)]6[Fe(CN)6]}[Fe(CN)6]·6CH3OH (3) and [Mn(L2)(H2O)]6[Cr(CN)6]}[Cr(CN)6]·6CH3OH (4); and two two-dimensional M−MnIII networks, [H3O][Mn(L1)]2[Fe(CN)6]}·2DMF (5) and K[Mn(L1)]2[Cr(CN)6]}·1.5CH3CN·CH3OH (6) (L1 = N,N-ethyl

  一系列六种新的氰化物桥杂金属配合物，包括两种四核T型Fe III Mn III 3化合物，[Mn（L 1）（H 2 O）] 3 [Fe（CN）5（1-CH 3 im） ]} ClO 4 ·1.5H 2 O（1）和[Mn（L 2）（H 2 O）] 3 [Fe（CN）5（1-CH 3 im）]} ClO 4 ·3H 2 O（2）; 两种肝核笼形M III Mn III 6（M = Fe，Cr）化合物，[Mn（L2）（H 2 O）] 6 [Fe（CN）6 ]} [Fe（CN）6 ]·6CH 3 OH（3）和[Mn（L 2）（H 2 O）] 6 [Cr（CN ）6 ]} [Cr（CN）6 ]·6CH 3 OH（4）；和两个二维M-Mn III网络，[H 3 O] [Mn（L 1）] 2 [Fe（CN）6 ]}·2DMF（5）和K [Mn（L 1）] 2 [ Cr（CN）6 ]}·1.5CH
• Hydrogen-bond directed 2D cyanide-bridged coordination polymer assembled from a new pentacyanidecobalt(III) building block and a bicompartimental Schiff-base manganese(III) compound: Synthesis, structures and magnetic properties
  作者：Daopeng Zhang、Ping Wang

  DOI：10.1016/j.inoche.2012.09.013

  日期：2012.12

  Abstract With a new pentacyanidecobalt(III) precursor K2[Co(CN)5(CH3CN)] and a bicompartimental Schiff base manganese(III) compound, a new two-dimensional cyanide-bridged Co(III)-Mn(III) coordination polymer constructed by hydrogen-bond interactions has been successfully synthesized and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. Single X-ray diffraction

  摘要 使用新型五氰钴 (III) 前驱体 K2[Co(CN)5(CH3CN)] 和双室席夫碱锰 (III) 化合物，一种新型二维氰化物桥连 Co(III)-Mn(III) 配位聚合物已成功合成并通过元素分析、红外光谱和 X 射线结构测定对其进行了表征。单次 X 射线衍射分析表明，这种阳离子氰化物桥连四核复合物是通过来自一个复合物的配位水配体和来自相邻复合物的游离 O4 区室进行自我互补的，从而提供了有趣的 2D 超分子结构。对磁化率的研究揭示了相邻 Mn(III) 离子之间的整体弱反铁磁耦合。
• Synthesis, structure, magnetic properties and DFT calculations of two hydroxo-bridged complexes based on MnIII(Schiff-Bases)
  作者：Hong-Bo Zhou、Hui-Sheng Wang、Ying Chen、Yong-Lu Xu、Xiao-Jiao Song、You Song、Yi-Quan Zhang、Xiao-Zeng You

  DOI：10.1039/c0dt01544j

  日期：——

  hydroxo-bridged complexes, [MnIII(3-CH3O)salen]2[CrIII(salen)(OH)2]}ClO4·6H2O (1) and [MnIII(5-CH3)salen]2(OH)}ClO4·3H2O (2) [salen = N,N′-ethylenebis(salicylideneiminato) dianion], have been synthesized by the hydrolysis of the corresponding MnIII(Schiff-Bases) derivatives and [Cr(salen)(H2O)2]Cl precursors. X-Ray structure characterization reveals the discrete linear arched trinuclear structure of 1 and

  两种羟基桥接的络合物，[Mn III（3-CH 3 O）salen] 2 [Cr III（salen）（OH）2 ]} ClO 4 ·6H 2 O（1）和[Mn III（5-CH 3）salen] 2（OH）} ClO 4 ·3H 2 O（2）[salen = N，N'-亚乙基双（水杨酰亚胺亚氨基）二价阴离子]，是通过水解相应的Mn III（席夫碱）衍生物合成的和[Cr（salen）（H 2 O）2] Cl前体。X射线结构表征揭示的离散线性拱形三核结构1和的一维链排列2。磁性实验数据和密度泛函理论（DFT）的计算均表明1和2中的羟基桥介导的主要反铁磁相互作用。频率相关的交流磁化率表明低温下1的缓慢弛豫。值得一提的是，的结构和磁特性1相当于一个报告的氰桥SMM，K [（5- Brsalen）2（H 2 O）2的Mn 2的Cr（CN）6]·2H 2 O.
• Synthesis, crystal structure and magnetic properties of a new 2D cyanide-bridged heterobimetallic Cr(I)–Mn(III) complex
  作者：Daopeng Zhang、Li-Fang Zhang、Hailong Wang、Yuting Chen、Zhong-Hai Ni、Jianzhuang Jiang

  DOI：10.1016/j.inoche.2010.04.030

  日期：2010.7

  new two-dimensional cyanide-bridged Cr(I)–Mn(III) coordination polymer K[Mn(L)]2[Cr(CN)5NO]}·CH3CN (1) (L = N,N-ethylene-bis(3-methoxysalicylideneiminate)) has been successfully synthesized by the reaction of K3[Cr(CN)5NO] with [Mn(L)(H2O)2]ClO4 and characterized by elemental analysis, FT-IR and X-ray structure determination. Investigation systematic over magnetic susceptibility of the complex reveals

  摘要 一种新型二维氰化物桥连 Cr(I)–Mn(III) 配位聚合物 K[Mn(L)]2[Cr(CN)5NO]}·CH3CN (1) (L = N,N-乙烯通过K3[Cr(CN)5NO]与[Mn(L)(H2O)2]ClO4反应成功合成-双(3-甲氧基水杨亚胺))，并通过元素分析、FT-IR和X射线结构表征决心。对配合物磁化率的系统研究揭示了氰化物桥连的 Cr(I) 离子和 Mn(III) 离子之间的整体反铁磁相互作用及其 3D 反铁磁有序行为，具有低于 12.5 K 的典型变磁性特征。
• Synthesis, crystal structures and magnetic properties of three pentanuclear cyanide-bridged heterometallic complexes
  作者：Daopeng Zhang、Lifang Zhang、Zengdian Zhao、Xia Chen、Zhonghai Ni

  DOI：10.1016/j.ica.2011.08.002

  日期：2011.11

  Three dicyanide-containing building blocks and one manganese(III) compound based on bicompartimental Schiff base ligand have been employed to assemble cyanide-bridged heterometallic complexes, resulting in three cyanide-bridged M-III-Mn-III (M = Fe, Cr, Co) complexes: K[Mn(L)(CH3OH)][Fe(bpb)]}(2)}ClO4 center dot H2O (1), K[Mn(L)(CH3OH)][Cr(bpb)]}(2)}ClO4 center dot CH3OH (2) and K[Mn(L)(CH3OH)][Co(bpb)]}(2)}ClO4 center dot H2O (3) (bpb(2) = 1,2-bis(pyridine-2-carboxamido)benzenate, L = N,N-ethylene-bis(3-methoxysalicylideneiminate). Single X-ray diffraction analysis shows their very similar pentanuclear structures consisting of two same units [Mn(L)(CH3OH)][Fe(bpb)]} linked by K+ complexed to eight phenolic oxygen atoms. The coordination geometry for both of the M(III) and Mn(III) ion in all the complexes is a slightly distorted octahedron. Investigation over magnetic properties of complexes 1 and 2 reveals the antiferromagnetic magnetic coupling between the neighboring Fe(Cr)(III) and Mn(III) ions through the bridging cyanide group. A best-fit to the magnetic susceptibilities of these two complexes leads to the magnetic coupling constants J = -1.65(2) (1) and -0.99(1) cm (1) (2), respectively. (C) 2011 Elsevier B. V. All rights reserved.