[RuBr(PPh3)(CH3(Cl)(O)C6H2C(C6H5)=N-p-C6H4NO2)2] | 926627-92-1

• 英文名称: [RuBr(PPh3)(CH3(Cl)(O)C6H2C(C6H5)=N-p-C6H4NO2)2]
• CAS: 926627-92-1
• 化学式: C₅₈H₄₃BrCl₂N₄O₆PRu
• 分子量: 1174.86
• InChiKey: TYDHJNSKGXARNE-LPTBCCRZSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [bis(triphenylphosphine) (methanol) ruthenium(III) tribromide] 、 CH3(Cl)(OH)C6H2C(C6H5)=N-p-NO2C6H4 以 苯 为溶剂， 生成 [RuBr(PPh3)(CH3(Cl)(O)C6H2C(C6H5)=N-p-C6H4NO2)2]
  参考文献：
  名称：

  Ruthenium(III) bis-bidentate Schiff base complexes mediated transfer hydrogenation of imines

  摘要：

  The mono anionic bidentate Schiff base ligands of N, O bonding system has been employed to synthesize a series of new stable ruthenium(III) complexes of general composition [RuX(EPh3)(L)(2)] (where, E = P or As, X = Cl or Br and L = O, N donor of Schiff bases). All the complexes have been fully characterized by elemental analyses, magnetic susceptibility measurements, FT-IR, UV-Vis, EPR and cyclic voltammetric techniques. The catalytic reactivity explored proving these complexes to be efficient in the transfer hydrogenation of imines to amines with moderate to high conversions. (C) 2006 Elsevier B.V, All rights reserved.

  DOI：

  10.1016/j.inoche.2006.04.012