| 440366-18-7

• CAS: 440366-18-7
• 化学式: C₃₆H₃₇IMoO₂P₂
• 分子量: 786.481
• InChiKey: GFWMUZIANVMOBQ-FLMYPBEOSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 potassium iodide 在 silver tetrafluoroborate 作用下， 以 丙酮 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Investigations on the trigonal twist process in the pseudooctahedral complexes [MX(CO)2(PP)(η3-R)] (M=Mo or W; X=halide or pseudohalide; PP=bidentate P-donor ligand; R=cycloheptatrienyl, cyclohexenyl or cyclooctenyl)

  摘要：

  A series of complexes [MX(CO)(2)(P-P)(eta(3)-R)] [M = Mo or W; X = halide, NCO or NCS; P-P = Ph2P(CH2)(n)PPh2 (n = 1-3)] have been prepared. Variable temperature P-31{H-1}-NMR investigations reveal the operation of a trigonal twist fluxional process in complexes where R = cycloheptatrienyl (C7H7), cyclohexenyl (C6H9) or cyclooctenyl (C8H13) with DeltaG(C)(double dagger) (the free energy of activation at the temperature of coalescence) strongly R-dependent. Using the cycloheptatrienyl complexes [MX(CO)(2){PhP(CH2)(n)PPh2}(eta(3)-C7H7)] detailed investigations have been made to establish the effect on DeltaG(C)(double dagger) of variation of X, n and M. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(01)01355-9