benzyl 3-phenyl-9H-carbazole-9-carboxylate | 1197055-44-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: benzyl 3-phenyl-9H-carbazole-9-carboxylate
• 英文别名: Benzyl 3-phenylcarbazole-9-carboxylate
• CAS: 1197055-44-9
• 化学式: C₂₆H₁₉NO₂
• 分子量: 377.442
• InChiKey: DELLIPZUAUVFGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.65
• 重原子数：
  29.0
• 可旋转键数：
  3.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  31.23
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  benzyl 6-phenyl-3,4-dihydro-1H-carbazole-9(2H)-carboxylate 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 苯 为溶剂， 反应 1.0h， 以86%的产率得到benzyl 3-phenyl-9H-carbazole-9-carboxylate
  参考文献：
  名称：

  Aryl Hydrazide beyond as Surrogate of Aryl Hydrazine in the Fischer Indolization: The Synthesis of N-Cbz-indoles, N-Cbz-carbazoles, and N,N′-Bis-Cbz-pyrrolo[2,3-f]indoles

  摘要：

  Aryl hydrazides underwent the Fischer indolization reactions, while the N-carbamate group(s) remained intact to directly provide N-Cbz-indoles. This new method allowed the synthesis of various N-Cbz-carbazoles and N,N'-bis-Cbz-pyrrolo[2,3-f]indoles.

  DOI：

  10.1021/ol902250x

文献信息

• ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：DOOSAN CORPORATION

  公开号：US20210135118A1

  公开（公告）日：2021-05-06

  The present disclosure relates to a novel organic compound which has excellent thermal stability, electron transporting ability, and light emitting ability, and to an organic EL device containing the same. As the organic compound is used in an organic material layer of the organic EL device, the thermal stability, luminous efficiency, driving voltage, and life of the device can be improved.