[(η(5)-C5Me5)(CO)2FeAs(H)C(Ph)NMe2]BF4 | 352201-46-8

• 英文名称: [(η(5)-C5Me5)(CO)2FeAs(H)C(Ph)NMe2]BF4
• CAS: 352201-46-8
• 化学式: BF₄*C₂₁H₂₇AsFeNO₂
• 分子量: 543.024
• InChiKey: BDMLXLZCQPTWJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrafluoroboric acid 、 (E)-(η5-C5Me5)(CO)2FeAsC(Ph)NMe2 以 乙醚 为溶剂， 以92%的产率得到[(η(5)-C5Me5)(CO)2FeAs(H)C(Ph)NMe2]BF4
  参考文献：
  名称：

  Synthese, Struktur und Reaktivität des Ferrioarsaalkens [(η5-C5Me5)(CO)2FeAs=C(Ph)NMe2]

  摘要：

  Reaction of equimolar amounts of the carbenium iodide [Me2N(Ph)CSMe]I and LiAs(SiMe3)(2) . 1.5THF afforded the thermolabile arsaalkene Me3SiAs = C(Ph)NMe2 (1), which in situ was converted into the black crystalline ferrioarsaalkene [(eta (5)-C5Me)(Co)(2)FeAs=C(Ph)NMe2)] (2) by treatment with [(eta (5)-CSMe2)(CO)(2)FeCl]. Compound 2 was protonated by ethereal HBF4 to yield [(eta (5)-CsMe5)(Co)(2)FeAs(H)C(Ph)NMe2] BF4 (3) and methylated by CF3SO3Me to give [(eta (5)-C5Me5)(CO)(2)Fe As(Me)C(Ph)NMe2] - SO3CF3 (4). [(eta (5)-C5Me5)(Co)(2)FeAs[M(CO)(n)]C(Ph)NMe2] (5: [M(CO)(n)] = [Fe(CO)(4)]: 6: [Cr(CO)(5)]) were isolated from the reaction of 2 with [Fe-2(CO)PI or [{(Z)-cyclooctene}Cr(CO)(5)], respectively. Compounds 2-6 were characterized by means of elemental analyses and spectroscopy (IR, H-1, C-13{H-1}-NMR). The molecular structure of 2 was determined by X-ray diffraction analysis.

  DOI：

  10.1002/1521-3749(200105)627:5<863::aid-zaac863>3.0.co;2-j