5-carboxy-2,3,3-trimethyl-3H-indolium chloride | 1134308-39-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5-carboxy-2,3,3-trimethyl-3H-indolium chloride
• 英文别名: 2,3,3-trimethylindol-1-ium-5-carboxylic acid;chloride
• CAS: 1134308-39-6
• 化学式: C₁₂H₁₃NO₂*ClH
• 分子量: 239.702
• InChiKey: WKQLIURZQDVOQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.19
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  51.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-carboxy-2,3,3-trimethyl-3H-indolium chloride 、 3-(1-methyl-1H-indol-3-yl)prop-2-enal 以 N,N-二甲基甲酰胺 为溶剂， 反应 17.0h， 生成 10,10-dimethyl-8-(1-methyl-1H-indol-3-yl)-10H-pyrido[1,2-a]indolium-2-carboxylate
  参考文献：
  名称：

  [EN] PHENYLPYRIDO [1,2-A] INDOLIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISING THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE
  [FR] COLORANT THIOL/DISULFURE DÉRIVÉ DE PHÉNYLPYRIDO [1,2-A] INDOLIUM, COMPOSITION COLORANTE COMPRENANT LEDIT COLORANT, PROCÉDÉ D'ÉCLAIRCISSEMENT DE MATÉRIAUX À BASE DE KÉRATINE AU MOYEN DE CE COLORANT

  摘要：

  公开号：

  WO2009037324A3

文献信息

• PHENYLPYRIDO [1,2-A] INDOLIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISING THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE
  申请人：GREAVES Andrew

  公开号：US20120266392A1

  公开（公告）日：2012-10-25

  The invention relates to the dyeing of keratin materials using phenylpyrido[1,2-a]indolinium-derived thiol and disulfide fluorescent dyes. The invention relates to a dye composition comprising a phenylpyrido[1,2-a]indolinium-derived-chromophore thiol or disulfide dye and to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers, such as the hair, using said composition. It similarly relates to novel phenylpyrido[1,2-a]indolinium-derived-chromophore thiol dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  本发明涉及使用苯基吡咯[1,2-a]吲哚基硫醇和二硫化物荧光染料染色角蛋白质材料。本发明涉及一种染料组成物，包括苯基吡咯[1,2-a]吲哚基色团硫醇或二硫化物染料，并且涉及使用该组成物对角蛋白质材料进行染色过程，特别是角蛋白质纤维，尤其是人类角蛋白质纤维，如头发，具有美白效果。它同样涉及新的苯基吡咯[1,2-a]吲哚基色团硫醇染料及其在美白角蛋白质材料方面的应用。该组成物可使得在深色角蛋白质纤维上获得特别耐用和明显的美白效果。
• Phenylpyrido [1,2-A] indolium-derived thiol/disulfide dye, dye composition comprising this dye, process for lightening keratin materials using this dye
  申请人：Greaves Andrew

  公开号：US08398722B2

  公开（公告）日：2013-03-19

  The invention relates to the dyeing of keratin materials using phenylpyrido[1,2-a]indolinium-derived thiol and disulfide fluorescent dyes. The invention relates to a dye composition comprising a phenylpyrido[1,2-a]indolinium-derived-chromophore thiol or disulfide dye and to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers, such as the hair, using said composition. It similarly relates to novel phenylpyrido[1,2-a]indolinium-derived-chromophore thiol dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  本发明涉及使用苯基吡咯[1,2-a]吲哚啉衍生的巯基和二硫键荧光染料对角蛋白质材料进行染色。该发明涉及一种染料组合物，包括苯基吡咯[1,2-a]吲哚啉衍生的色团巯基或二硫键染料，并使用该组合物对角蛋白质材料进行染色，特别是角蛋白质纤维，尤其是人类角蛋白质纤维，如头发，具有漂白效果。本发明还涉及新型苯基吡咯[1,2-a]吲哚啉衍生的色团巯基染料及其在漂白角蛋白质材料中的用途。该组合物可在深色角蛋白质纤维上获得特别耐用和明显的漂白效果。
• PHENYLPYRIDO [1,2-A]INDOLIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISING THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE
  申请人：L'Oréal

  公开号：EP2193172B1

  公开（公告）日：2013-05-01
• PHENYLPYRIDO Ý1,2-A¨INDOLIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISING THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE
  申请人：L'Oréal

  公开号：EP2193172A2

  公开（公告）日：2010-06-09
• US8398722B2
  申请人：——

  公开号：US8398722B2

  公开（公告）日：2013-03-19