| 1423708-11-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1423708-11-5
• 化学式: C₃₁H₃₀N₄
• 分子量: 458.606
• InChiKey: MWDDGSUOIPVMGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.57
• 重原子数：
  35.0
• 可旋转键数：
  7.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  43.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 、 三苯基膦 以 二氯甲烷 为溶剂， 反应 3.0h， 以60%的产率得到
  参考文献：
  名称：

  Copper-containing copolymers based on the norbornene monomers. Synthesis, photo-, and electroluminescent properties

  摘要：

  New copper(I) complexes containing the norbornene-substituted phenanthroline ligand were synthesized. Based on these compounds, new carbon-chain copper-containing copolymers possessing the photo- and electroluminescent properties were obtained by the metathesis polymerization.

  DOI：

  10.1134/s107036321301012x
• 作为产物：
  描述：

  5-(5-bromopent-1-yl)bicyclo[2.2.1]hept-2-ene 、 2-phenyl-1H-imidazo[4,5-f ][1,10]phenanthroline 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 14.0h， 生成 、
  参考文献：
  名称：

  Copper-containing copolymers based on the norbornene monomers. Synthesis, photo-, and electroluminescent properties

  摘要：

  New copper(I) complexes containing the norbornene-substituted phenanthroline ligand were synthesized. Based on these compounds, new carbon-chain copper-containing copolymers possessing the photo- and electroluminescent properties were obtained by the metathesis polymerization.

  DOI：

  10.1134/s107036321301012x

文献信息

• Norbornene-Substituted Cationic Iridium(III) Complex and Water-Soluble Luminescent Polymers Based on It: Synthesis, Photophysical and Cytotoxic Properties
  作者：Yu. P. Parshina、T. A. Kovylina、A. N. Konev、A. A. Belikov、P. O. Baber、A. D. Komarova、E. A. Romaeva、L. N. Bochkarev

  DOI：10.1134/s1070363222120167

  日期：2022.12

  A norbornene-substituted cationic iridium(III) complex containing 1-phenylisoquinoline cyclometalating ligands and an additional phenylimidazophenanthroline ligand was synthesized. On the base of this complex, water-soluble polymers were obtained by ring-opening metathesis polymerization (ROMP). The resulting polymers showed oxygen-dependent phosphorescence in the orange spectral region and high cytotoxicity against HCT116 cancer cells.

  摘要 合成了一种降冰片烯取代的阳离子铱（III）配合物，该配合物含有 1-苯基异喹啉环甲基化配体和一个附加的苯基咪唑菲配体。在该配合物的基础上，通过开环偏聚聚合反应（ROMP）获得了水溶性聚合物。得到的聚合物在橙色光谱区显示出氧依赖性磷光，对 HCT116 癌细胞具有很强的细胞毒性。