4-[4-(10-Methoxy-1',1',5',5'-tetramethyl-5-phenylspiro[6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8(13),9,11,15,17,19-nonaene-21,3'-cyclohexane]-5-yl)phenyl]morpholine | 1161433-67-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: 4-[4-(10-Methoxy-1',1',5',5'-tetramethyl-5-phenylspiro[6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8(13),9,11,15,17,19-nonaene-21,3'-cyclohexane]-5-yl)phenyl]morpholine
• CAS: 1161433-67-5
• 化学式: C₄₆H₄₇NO₃
• 分子量: 661.884
• InChiKey: QQFFSNODSXGWOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  50
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• PHOTOCHROMIC COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20160222285A1

  公开（公告）日：2016-08-04

  A photochromic composition comprising (A) a polyrotaxane having a composite molecular structure composed of an axial molecule and a plurality of cyclic molecules clathrating the axial molecule and (B) a photochromic compound.

  一种光致变色组合物，包括(A)聚轮烷，其具有由轴向分子和多个环状分子组成的复合分子结构，并且(B)光致变色化合物。
• PHOTOCHROMIC CURABLE COMPOSITION, CURED PRODUCT THEREOF AND LAMINATE INCLUDING THE CURED PRODUCT
  申请人：TOKUYAMA CORPORATION

  公开号：US20160002524A1

  公开（公告）日：2016-01-07

  A curable composition which comprises a carbonate-based polymerizable monomer represented by the following formula, other polymerizable monomers and a photochromic compound, can be used even under high-temperature and high-humidity conditions without any problems and provides a cured product having excellent photochromic properties. wherein A and A′ are each a linear or branched alkylene group having 2 to 15 carbon atoms, “a” is an average value of 1 to 20, when there are a plurality of A's, A's may be the same or different, R 1 is a hydrogen atom or methyl group, and R 2 is a (meth)acryloyloxy group or hydroxyl group.

  可治愈组合物包括以下化学式所表示的碳酸酯基可聚合单体、其他可聚合单体和光致变色化合物，即使在高温高湿环境下也可以使用，而且提供具有出色光致变色性能的固化产物。其中，A和A'是具有2至15个碳原子的线性或支链烷基，"a"是1至20的平均值，当有多个A时，A可以相同或不同，R1是氢原子或甲基基团，R2是（甲基）丙烯酰氧基团或羟基。
• COATING COMPOSITION, PROCESS FOR PRODUCTION OF THE COMPOSITION, AND LAMINATE WITH HARD COAT LAYER
  申请人：Tokuyama Corporation

  公开号：EP2377902A1

  公开（公告）日：2011-10-19

  [Abstract] To provide a coating composition capable of forming a hard coat layer having excellent transparency and scratch resistance on the surface of an optical resin substrate such as a plastic lens, and exhibiting long-term storage stability. [Means for Solution] The coating composition comprises (A) a fine particulate composite metal oxide, (B') a hydrolyzed product obtained by the hydrolysis of (B) a hydrolyzable organosilicon compound containing (B1) an organosilicon compound that has an epoxy group, such as γ-glycidoxypropyltrimethoxysilane, (C) water, (D1) a low-boiling lowly viscous alcohol having not more than 3 carbon atoms, such as methanol or ethanol, (D2) a low-boiling highly viscous alcohol such as t-butanol, (D3) a high-boiling organic solvent having a boiling point of 150°C to 200°C, such as diacetone alcohol, and (E) a curing catalyst such as tris(2,4-pentanedionato)aluminum(III), the mass ratio (D1/C) of the component (D1) and the component (C) being in a range of 1.80 to 7.00, the mass ratio (D2/C) of the component (D2) and the component (C) being in a range of 0.24 to 2.50, and the mass ratio (D3/C) of the component (D3) and the component (C) being in a range of 1.10 to 4.40.

  [摘要] 提供一种涂层组合物，该涂层组合物能够在塑料透镜等光学树脂基材表面形成具有优异透明度和抗划伤性的硬涂层，并具有长期储存稳定性。 [解决方法] 涂层组合物包括 (A) 细颗粒复合金属氧化物；(B') 由 (B) 可水解有机硅化合物水解得到的水解产物，该有机硅化合物含有 (B1) 具有环氧基团的有机硅化合物，如 γ-缩水甘油氧丙基三甲氧基硅烷；(C) 水；(D1) 具有不超过 3 个碳原子的低沸点低粘度醇、(D3) 沸点为 150°C 至 200°C 的高沸点有机溶剂，如二丙酮醇，以及 (E) 固化催化剂，如三(2,4-戊二酮酸)铝(III)，组分 (D1) 和组分 (C) 的质量比 (D1/C) 在 1.80至7.00，组分(D2)和组分(C)的质量比(D2/C)在0.24至2.50之间，组分(D3)和组分(C)的质量比(D3/C)在1.10至4.40之间。
• PRIMER COMPOSITION FOR OPTICAL ARTICLES, AND OPTICAL ARTICLE
  申请人：Tokuyama Corporation

  公开号：EP2420543A1

  公开（公告）日：2012-02-22

  A primer coating composition is provided for an optical article capable of forming a coating layer having excellent impact resistance, abrasion resistance, and adhesion to various kinds of plastic materials without occurring of appearance faulty for an optical base material, for example, a plastic lens for an eyeglass. A primer composition for an optical article comprises; (A) aqueous dispersion of urethane resin having a polycarbonate-derived skeleton and the elongation of 200 ∼ 1000%; (B) an organic solvent having 3 ∼ 9 carbon atoms and having an ether bond or carbonyl bond and one hydroxyl group in a molecule; and (C) lower alcohol having 1 ∼ 4 carbon atoms, wherein the weight ratio of said organic solvent to said lower alcohol is from 0.01 to less than 2.00.

  提供了一种用于光学产品的底涂层组合物，该组合物能够形成对各种塑料材料具有优异抗冲击性、耐磨性和附着力的涂层，而不会使光学基底材料（例如眼镜的塑料镜片）出现外观缺陷。用于光学产品的底层涂料组合物包括：(A) 具有聚碳酸酯衍生骨架且伸长率为 200 ∼ 1000% 的聚氨酯树脂的水分散液；(B) 具有 3 ∼ 9 个碳原子且分子中具有一个醚键或羰基键和一个羟基的有机溶剂；以及 (C) 具有 1 ∼ 4 个碳原子的低级醇，其中所述有机溶剂与所述低级醇的重量比为 0.01 至小于 2.00。
• COATING COMPOSITION
  申请人：Tokuyama Corporation

  公开号：EP2423281A1

  公开（公告）日：2012-02-29

  [Problem] To provide a coating composition for forming a hard coating which, by itself, favorably adheres to a plastic optical substrate, and effectively prevents the occurrence of cracks caused by the thermal hysteresis at the time of curing. [Means for Solution] The coating composition for forming a hard coating, contains a fine inorganic oxide particle, a hydrolyzable organosilicon compound, water, a curing catalyst and an organic solvent, wherein cyclic ketone is contained in an amount of 0.10 parts by mass to 30.00 parts by mass per 100 parts by mass of the total of the fine inorganic oxide particle and the hydrolyzable organosilicon compound.

  [问题]提供一种用于形成硬涂层的涂层组合物，该涂层组合物本身有利于附着在塑料光学基材上，并有效防止固化时由于热滞后而产生的裂纹。 [解决方法] 这种用于形成硬涂层的涂料组合物含有细无机氧化物颗粒、可水解有机硅化合物、水、固化催化剂和有机溶剂，其中环酮的含量为细无机氧化物颗粒和可水解有机硅化合物的总和每 100 份质量中 0.10 份至 30.00 份质量。