| 791629-98-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 791629-98-6
• 化学式: C₁₆H₃₈IrNP₂
• 分子量: 498.652
• InChiKey: SGUSSMYZWBWAHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 异丙醇 以 四氢呋喃 为溶剂， 以84%的产率得到(HN(iPr₂PC₂H₄)2)IrH₃
  参考文献：
  名称：

  A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones

  摘要：

  The air-stable iridium chlorodihydride complex IrH2Cl[((Pr2PC2H4)-Pr-i)(2)NH], 1, was prepared from the reaction of [IrCl(coe)(2)](2) with the pincer ligand ((Pr2PC2H4)-Pr-i)(2)NH in 2-propanol at 80 degrees C. Reaction of 1 with (KOBu)-Bu-t in THF resulted in the formation of the air-sensitive amidodihydride complex IrH2[((Pr2PC2H4)-Pr-i)(2)N], 2, which in the presence of 2-propanol readily forms the moderately air-stable trihydride complex IrH3[((Pr2PC2H4)-Pr-i)(2)NH], 3. The trihydride and amidodihydride complexes in the absence of a base are exceptionally active catalysts for the transfer hydrogenation of ketones in 2-propanol.

  DOI：

  10.1021/om060049z
• 作为产物：
  描述：

  IrH₂Cl[(iPr₂PC₂H₄)2NH] 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到
  参考文献：
  名称：

  A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones

  摘要：

  The air-stable iridium chlorodihydride complex IrH2Cl[((Pr2PC2H4)-Pr-i)(2)NH], 1, was prepared from the reaction of [IrCl(coe)(2)](2) with the pincer ligand ((Pr2PC2H4)-Pr-i)(2)NH in 2-propanol at 80 degrees C. Reaction of 1 with (KOBu)-Bu-t in THF resulted in the formation of the air-sensitive amidodihydride complex IrH2[((Pr2PC2H4)-Pr-i)(2)N], 2, which in the presence of 2-propanol readily forms the moderately air-stable trihydride complex IrH3[((Pr2PC2H4)-Pr-i)(2)NH], 3. The trihydride and amidodihydride complexes in the absence of a base are exceptionally active catalysts for the transfer hydrogenation of ketones in 2-propanol.

  DOI：

  10.1021/om060049z