(kappa.0-hydrotris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)2(H)2 | 381223-61-6

• 英文名称: (kappa.0-hydrotris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)2(H)2
• CAS: 381223-61-6
• 化学式: C₁₂H₃₈P₄Rh*C₁₅H₂₂BN₆
• 分子量: 706.425
• InChiKey: TVEOGHOBEOUKEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (kappa.3-N,N',N''-hydrotris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)(H)2 、 三甲基膦 以 四氢呋喃 为溶剂， 生成 (kappa.0-hydrotris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)2(H)2
  参考文献：
  名称：

  Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: Fromκ3- to Ionic “κ0”-Tp′

  摘要：

  Isolated hydrotris(pyrazolyl)borate anions Tp' were obtained as salts of metal complex cations (see picture) by the displacement of Rh-coordinated kappa(3)-N,N',N"-Tp' by PMe(3) (Tp'=Tp and Tp(Me2)). With [(kappa(3)-Tp(Me2))Rh(C(2)H(4))(2)], stepwise diplacement of the Tp(Me2) ligand allowed the isolation of complexes exhibiting the kappa(2)- Tp(Me2) and kappa(1)-Tp(Me2) coordination modes.

  DOI：

  10.1002/(sici)1521-3773(20000103)39:1<218::aid-anie218>3.0.co;2-f