N-[4-[10-[4-(N-(9,9-diethylfluoren-2-yl)anilino)phenyl]anthracen-9-yl]phenyl]-9,9-diethyl-N-phenylfluoren-2-amine | 1200553-66-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: N-[4-[10-[4-(N-(9,9-diethylfluoren-2-yl)anilino)phenyl]anthracen-9-yl]phenyl]-9,9-diethyl-N-phenylfluoren-2-amine
• CAS: 1200553-66-7
• 化学式: C₇₂H₆₀N₂
• 分子量: 953.282
• InChiKey: YJPHDTBSOGBDLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.3
• 重原子数：
  74
• 可旋转键数：
  12
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,10-bis(4-(phenylamino)phenyl)anthracene 、 2-溴-9,9-二乙基芴 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 15.0h， 以11%的产率得到N-[4-[10-[4-(N-(9,9-diethylfluoren-2-yl)anilino)phenyl]anthracen-9-yl]phenyl]-9,9-diethyl-N-phenylfluoren-2-amine
  参考文献：
  名称：

  Arylamino-9,10-diphenylanthracenes for organic light emitting devices

  摘要：

  Hole-transporting arylamino-9,10-diphenylanthracene derivatives were synthesized by C-N cross coupling with palladium catalyst. The materials showed higher glass transition temperatures (135-177 degrees C) than that of a conventional hole-transporting material, N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)benzidine (NPD). The compounds all showed higher hole mobilities than that of NPD, with one of the compounds showing a much higher hole mobility of similar to 1.0 x 10(-2) cm(2) V(-1)s(-1). Tris-(8-quinolinolato) aluminum (Alq(3))-based green light emitting devices containing the arylamino-9,10-diphenylanthracene derivatives as hole transport layers were fabricated. The devices containing the anthracene derivatives showed lower driving voltages and higher efficiencies compared with those of the equivalent device containing NPD. The anthracene derivative with a dibenzofuran substituent was also used as the emitting material in a device. This device emitted blue light with high efficiencies of 5.0 lm/W and 6.3 cd/A at 4.0 V and 1000 cd/m(2), respectively. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2009.12.001