[Mn2(tert-butylphosphonic acid(-1H))4(2,2'-bipyridine)2] | 1144031-85-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Mn2(tert-butylphosphonic acid(-1H))4(2,2'-bipyridine)2]
• 英文别名: [Mn2(tert-butylphosphonic acid(-1H))4(bipy)2]
• CAS: 1144031-85-5
• 化学式: C₃₆H₅₆Mn₂N₄O₁₂P₄
• 分子量: 970.631
• InChiKey: SHHQNCUTQWTWQV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 叔丁基磷酸 、 manganese (II) acetate tetrahydrate 在 acetic acid 作用下， 以 甲醇 、 乙腈 为溶剂， 以21%的产率得到[Mn2(tert-butylphosphonic acid(-1H))4(2,2'-bipyridine)2]
  参考文献：
  名称：

  Synthesis and characterization of two manganese tert-butylphosphonate complexes

  摘要：

  Two manganese(II) phosphonate complexes, Mn-2(t-BuPO3H)(4)(bipy)(2) 1 (bipy = 2,2'-bipyridine) and [Mn (H2O)(6)][t-BuPO3H](2)center dot 6H(2)O 2 have been synthesized with identical procedure from similar system containing tert-butylphosphonic acid and bipy ligands in different ratio at different temperature. The complexes have been characterized by single crystal X-ray diffraction, IR spectroscopy, X-ray powder diffraction, magnetic measurement and thermal analysis. Compound I crystallizes in the triclinic space group P-1 with C-2v symmetry, and exhibits infinite double-chains linked by hydrogen bonds and the double-chains are further packed into two-dimensional network via the pi-pi stacking interactions, whereas compound 2 crystallizes in a monoclinic space group P-2(1)/c, and the mononuclear molecules in 2 are linked by hydrogen bonds to form sandwich-like two-dimensional formation. The magnetic measurement reveals weak antiferromagnetic exchange interactions between the manganese(II) ions in compound 1. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.11.008