neodymium tri-n-butoxide | 19236-00-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: neodymium tri-n-butoxide
• 英文别名: neodymium 1-butanolate；Einecs 242-902-9；butan-1-olate;neodymium(3+)
• CAS: 19236-00-1
• 化学式: C₁₂H₂₇NdO₃
• 分子量: 363.585
• InChiKey: LXWFJBAAYXIVRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.15
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  neodymium tri-n-butoxide 在 乙酰丙酮 作用下， 以 neat (no solvent) 为溶剂， 以85-95的产率得到neodymium(III) acetylacetonate
  参考文献：
  名称：

  Synthesis of yttrium, lanthanum, neodymium, praseodymium, and lutetium alkoxides and acetylacetonates

  摘要：

  A convenient and practical method is proposed for the synthesis of lanthanide and yttrium alkoxides. The method involves dissolving the metals or their hydrides in a solution of dry HCl in the corresponding alcohol, with subsequent dehalogenation of the LnCl3 solution by an equivalent amount of alkali metal (Na, Li), The rare-earth alkoxides are easily converted into acetylacetonates Ln(acac)3 by the action of acetylacetone.

  DOI：

  10.1007/bf00863354
• 作为产物：
  描述：

  neodymium (III) isopropoxide 生成 neodymium tri-n-butoxide
  参考文献：
  名称：

  Misra, S. N.; Misra, T. N.; Kapoor, R. N., Chemistry and industry

  摘要：

  DOI：

文献信息

• Fabrication of Single Crystalline Neodymium Oxide Nanowires under Mild Conditions
  作者：Yusuke Murata、Motonari Adachi

  DOI：10.1246/cl.2004.488

  日期：2004.5

  Nanowires of single crystalline neodymium oxide have been successfully synthesized under mild conditions using surfactant-assisted assemblies composed of laurylamine hydrochloride and neodymium alkoxide modified with acetylacetone. The nanowire structure was characterized by XRD, TEM, SEM, and nitrogen adsorption isotherms. Nd2O3 nanowires have a single crystalline structure with diameters ranging from 10 to 50 nm and lengths of several hundred nanometers. This newly developed synthetic method can be easily extended to other rare earth metal oxides.

  利用由盐酸月桂胺和用乙酰丙酮修饰的氧化钕组成的表面活性剂辅助组合物，在温和条件下成功合成了单晶氧化钕纳米线。通过 XRD、TEM、SEM 和氮吸附等温线对纳米线结构进行了表征。Nd2O3 纳米线具有单晶结构，直径为 10 至 50 纳米，长度为几百纳米。这种新开发的合成方法很容易推广到其他稀土金属氧化物。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D3, 2.6.2, page 26 - 27
  作者：

  DOI：——

  日期：——
• Misra, S. N.; Misra, T. N.; Kapoor, R. N., Chemistry and industry
  作者：Misra, S. N.、Misra, T. N.、Kapoor, R. N.、Mehrotra, R. C.

  DOI：——

  日期：——
• Carbon dioxide fixaion by lathanide complexes
  作者：M.N. Bochkarev、E.A. Fedorova、Yu.F. Radkov、S.Ya. Khorshev、G.S. Kalinina、G.A. Razuvaev

  DOI：10.1016/s0022-328x(00)99264-7

  日期：1983.11
• Synthesis of yttrium, lanthanum, neodymium, praseodymium, and lutetium alkoxides and acetylacetonates
  作者：V. V. Gavrilenko、L. A. Chekulaeva、I. A. Savitskaya、I. A. Garbuzova

  DOI：10.1007/bf00863354

  日期：1992.11

  A convenient and practical method is proposed for the synthesis of lanthanide and yttrium alkoxides. The method involves dissolving the metals or their hydrides in a solution of dry HCl in the corresponding alcohol, with subsequent dehalogenation of the LnCl3 solution by an equivalent amount of alkali metal (Na, Li), The rare-earth alkoxides are easily converted into acetylacetonates Ln(acac)3 by the action of acetylacetone.