[Cu(CH3CO2)(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4 | 176173-01-6

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [Cu(CH3CO2)(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4
• 英文别名: copper;N'-[2-(dimethylamino)ethyl]-N,N,N'-trimethylethane-1,2-diamine;acetate;perchlorate
• CAS: 176173-01-6
• 化学式: C₂H₃O₂*C₉H₂₃N₃*ClO₄*Cu
• 分子量: 395.343
• InChiKey: FOLMSOPUAORZNM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (octaethylporphinato)iron(III) perchlorate 、 [Cu(CH3CO2)(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4 以 二氯甲烷 为溶剂， 生成 [Fe(octaethylporphyrinate)(OH)Cu(OClO3)(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4 、 [Fe(octaethylporphyrinate(2-))(O2CH)] 、 [Fe(octaethylporphyrinate)(CH3CO2)Cu(1,1,4,7,7-pentamethyldiethylenetriamine)](ClO4)2
  参考文献：
  名称：

  Scott, Michael J.; Goddard, Christine A.; Holm, Inorganic Chemistry, 1996, vol. 35, # 9, p. 2558 - 2567

  摘要：

  DOI：
• 作为产物：
  描述：

  [CuCl(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4 、 sodium acetate 以 甲醇 为溶剂， 以81%的产率得到[Cu(CH3CO2)(1,1,4,7,7-pentamethyldiethylenetriamine)]ClO4
  参考文献：
  名称：

  Scott, Michael J.; Goddard, Christine A.; Holm, Inorganic Chemistry, 1996, vol. 35, # 9, p. 2558 - 2567

  摘要：

  DOI：

文献信息

• Copper(II) complexes of tridentate N,N,N′,N″,N″-pentamethyldiethylenetriamine: Superoxide dismutase and inhibitory activity against bacteria and fungi
  作者：R.N. Patel、Nripendra Singh、V.L.N. Gundla、U.K. Chauhan

  DOI：10.1016/j.saa.2006.04.017

  日期：2007.3

  A series of ternary copper(II) complexes containing same coordination sphere but difference in the counter ions, viz., [Cu(PMDT)(OAc)]PF6 (1); [Cu(PMDT)(OAc)]ClO4 (2); [Cu(PMDT)(OAc)]BF4 (3) and [Cu(PMDT)(OAc)]BPh4 (4) where PMDT=N,N,N',N'',N''-pentamethyldiethylenetriamine, OAc=Acetate ion were synthesized and characterized by means of spectroscopic, magnetic and cyclic voltammetric measurements. In frozen solution e.p.r. spectra, an interesting relation g(parallel to) > g(perpendicular to) has been observed which is a typical of the axially symmetric d(9) Cu-II (S-Cu = 1/2) having an unpaired electron in a d(x2-y2) orbital. Single crystal X-ray analysis of (1) has revealed the presence of distorted square planar geometry. The influence of the counter ion on the complexes has been examined by performing some biological experiments like superoxide dismutase and anti-microbial activity. (c) 2006 Elsevier B.V. All rights reserved.