Mn(TDCPβCl8P) | 134776-89-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Mn(TDCPβCl8P)
• CAS: 134776-89-9
• 化学式: C₄₄H₁₂Cl₁₆MnN₄
• 分子量: 1218.79
• InChiKey: CJXLJIVYJAHRHR-OEHKZIGDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) acetate 、 2,3,7,8,12,13,17,18-octachloro-5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 生成 Mn(TDCPβCl8P)
  参考文献：
  名称：

  Influence of manganese tetraarylporphyrins substituents on the selectivity of cycloalkanes oxidation with magnesium monoperoxyphthalate

  摘要：

  The catalytic properties of manganese porphyrins of the second and third generation and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in oxidation of cyclohexane or cyclooctane under mild conditions. We have found that the structure of manganese porphyrin has an influence on selectivity of the investigated reaction. Apart from main cycloalkanes oxidation products (alcohol and ketone), olefins and epoxides resulting from oxidative dehydrogenation of substrates in the course of reaction, were surprisingly found. This represents the first example of the oxidative dehydrogenation of cycloalkanes with MMPP as oxygen donor. The reaction mechanism is discussed and proposed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.04.070