3(5)-adamantyl-5(3)-isopropyl-1-pyrazole | 733752-93-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3(5)-adamantyl-5(3)-isopropyl-1-pyrazole
• CAS: 733752-93-7
• 化学式: C₁₆H₂₄N₂
• 分子量: 244.38
• InChiKey: CIOOJOOAWCUXSY-WTHWONHRSA-N

物化性质

• 沸点：
  375.8±11.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  钾硼氢 、 3(5)-adamantyl-5(3)-isopropyl-1-pyrazole 、 乙腈 以47%的产率得到potassium hydrotris(3-adamantyl-5-isopropyl-1-pyrazolyl)borate acetonitrile solvate
  参考文献：
  名称：

  The most hindered hydrotris(pyrazolyl)borate ligand, X-ray structure of chlorocopper(II) complex: [Cu(Cl){HB(3-Ad-5-Pripz)3}] as compared with [Cu(Cl){HB(3-But-5-Pripz)3}]

  摘要：

  Admantyl substituted hydrotris(pyrazolyl)borate ligand, which is the most hindered in all the hydrotris(pyrazolyl)borate ligands, is newly synthesized. Two chlorocopper(II) complexes with [HB(3-Ad-5-Pr(i)pz)(3)](-) and [HB(3-Bu-t-5-Pr(i)PZ)(3)](-) were characterized by X-ray diffraction and some spectroscopic techniques. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.10.030