cyclopenta-1,3-diene;5-ethyldec-5-ene;hafnium(4+) | 201158-36-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: cyclopenta-1,3-diene;5-ethyldec-5-ene;hafnium(4+)
• CAS: 201158-36-3
• 化学式: C₂₂H₃₂Hf
• 分子量: 474.986
• InChiKey: AIORDVBVJYLGQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二茂铪 、 5-癸炔 、 乙基溴化镁 以 四氢呋喃 为溶剂， 生成 cyclopenta-1,3-diene;5-ethyldec-5-ene;hafnium(4+)
  参考文献：
  名称：

  Preparation and reactions of Cp2HfRCl, Cp2HfRR′ and hafnacyclopent-2-enes

  摘要：

  Reaction of Cp2HfCl2 with R3Al (R = Et, n-Pr, or n-Bu) in hexane selectively produced monoalkylhafnocene complexes, Cp2HfRCl (1), in high yields. Cp2HfMeCl (la) was prepared by the reaction of oxo-bridged hafnocene complex (Cp2HfCl)(2)(mu-O) with Me3Al. The treatment of 1 with alkylating reagents such as R'Li or EtMgBr afforded unsymmetrical dialkylhafnocene complexes Cp2HfRR' (3) in good to excellent yields. The kinetic study of thermolysis of Cp2HfEtR (R = Me, Et, n-Bu, sec-Bu, t-Bu or Ph) suggested that decomposition of Cp2HfEt(sec-Bu) was much faster than the others. Cp2Hf(sec-Bu)(2) (2e) can be used as a good precursor of Cp2Hf(II) species. Hafnacyclopent-2-enes (4) were prepared in good yields by the reaction of Cp2HfEt2 (2b) with alkynes. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00375-6