| 24323-09-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 24323-09-9
• 化学式: C₂₁H₁₉FeN₃O₂
• 分子量: 401.248
• InChiKey: PPXGYMJCGKNWLA-SNTCFBDDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 甲苯 为溶剂， 生成 {Fe(salen)2}(18)O
  参考文献：
  名称：

  Nichols, Peter J.; Fallon, Gary D.; Murray, Keith S., Inorganic Chemistry, 1988, vol. 27, # 16, p. 2795 - 2800

  摘要：

  DOI：
• 作为产物：
  描述：

  在 pyridine 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  四价席夫碱配体稳定的铁（III）和铁（II）的高自旋有机金属衍生物

  摘要：

  席夫碱络合物的有机金属衍生物的制备和性质NN '-ethylenebis（水杨）铁（III），铁（SAEN）R（R =苯基，CH 2 PH）被报告。存在Fe（saen）COCH 3的实验证据，但未获得纯产物。在不同温度下的磁化率测量结果表明该化合物是高自旋的，是铁（III）的高自旋有机金属化合物的首例。准备工作包括用苄基氯处理[Fe（saen）] -阴离子或使苯基格氏试剂与碘衍生物Fe（saen）l反应。NN “-Ethylenebis（水杨）铁（II），Fe（saen），已显示与环己基异氰酸酯发生加成反应，得到1：1加合物Fe（saen）-CNC 6 H 11。Ir光谱和未能与一氧化碳获得相似的加合物的结果证实，与一氧化碳相比，异氰酸酯通常具有更差的π-受体和更好的σ-供体。

  DOI：

  10.1039/j19710003665

文献信息

• Synthesis and Magnetic Exchange Properties of Linear Trinuclear Oxo-Bridged MIIIORuIVOMIII Complexes (M = Fe, Cr, Mn) Formed by Two-Electron Redox Reactions
  作者：Kevin J. Berry、Boujemaa Moubaraki、Keith S. Murray、Peter J. Nichols、Lewis D. Schulz、Bruce O. West

  DOI：10.1021/ic00120a017

  日期：1995.8

  The two-electron reductions of various porphyrin complexes Ru-VI(O)(2)(P) by Fe(II), Cr(II), and Mn(II) compounds of porphyrins and salicylaldimines result in the formation of heterotrimetallic ore-bridged complexes (L)M(III)-ORuIV(P)OM(III)(L) (M = Fe(III), Cr(III), Mn(III); P is the dianion of 5,10,15,20-tetraarylporphyrins, such as tetraphenylporphyrin (TPP), tetrakis(p-methoxyphenyl)porphyrin (TMP), or 2,3,7,8,12,13,17,18-octaethylporphyrin (OEP); L is TPP, TMP, or OEP or the dianions of N,N'-(4-methyl-4-azaheptane-1,7-diyl)bis(salicylaldimine) (salmah) or N,N'-ethane-1,2-diylbis(salicylaldimine) (salen). A detailed study of the temperature- and field-dependent magnetic properties of this rather novel series of (L)M(III)ORu(IV)(P)OM(III)(L) compounds has been made. The spin-states of the constituent metal centers are as follows: Ru-IV, S-Ru = 1 (d(4)); Fe-III S-Fe = 5/2 (d(5)); Cr-III, S-Cr = 3/2 (d(3)); Mn-III, S-Mn = 4/2 (d(4)). The spin-state and coordination geometry of the (L)Fe-III groups were confirmed by Mossbauer spectral measurements. Trinuclear combinations of the present kind give rise to unusual coupled spin-state energy levels which, in the case of (L)(FeORuIV)-O-III(P)OFeIII(L) compounds, result in ''ferromagnetic-like'' plots of magnetic moment versus temperature, particularly at low temperatures. The following best-fit values of parameters were deduced from the magnetic moment data, obtained in 1 T fields over the temperature range 4.2-300 K. (salmah)FeORu(TPP)OFe(salmah): g = 1.97, J(12) = -19.7 cm(-1), J(13) = +6.5 cm(-1), alpha J(13)/J(12) = -0.33, ground-state S = 4; (TMP)FeORu(TPP)OFe(TMP): g = 1.95, J(12) = -23.4 cm(-1), J(13) = 5.4 cm(-1), alpha = -0.23, ground-state S = 4. (TPP)FeORu(TPP)OFe(TPP): g = 2.0, J(12) = -35.7 cm(-1), J(13) = 11.2 cm(-1), alpha = -0.31, ground-state S = 4, [(TPP)Fe]O-2 impurity = 13%, zero-field splitting of the S = 4 state (D cm approximate to 5 cm(-1)). (TMP)MnORu(TPP)OMn(TMP): g = 1.93, J(12) = -17.4 cm(-1), J(13) = 9.6 cm(-1), alpha = -0.55, groundstate S = 3. (TPP)CrORu(TPP)OCr(TPP): g = 1.98, J(12) = -25.3 cm(-1), J(13) = -11.1 cm(-1), alpha = 0.44, groundstate S = 1. Possible reasons for the small sizes of the J(12) values, in comparison to those of related M(III)OM(III) and (RuORuIV)-O-IV compounds, are discussed.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: Org.Verb.B1, 1.1.1.1.1.2, page 3 - 5
  作者：

  DOI：——

  日期：——
• Elliott, Robyn L.; West, Bruce O., Australian Journal of Chemistry, 1988, vol. 41, p. 1417 - 1424
  作者：Elliott, Robyn L.、West, Bruce O.

  DOI：——

  日期：——