4-morpholinylphosphonous dicyanide | 139556-39-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 4-morpholinylphosphonous dicyanide
• 英文别名: 4-Morpholinylphosphonous di-cyanide；[cyano(morpholin-4-yl)phosphanyl]formonitrile
• CAS: 139556-39-1
• 化学式: C₆H₈N₃OP
• 分子量: 169.123
• InChiKey: HAWVUCFJOUPUNF-UHFFFAOYSA-N

物化性质

• 沸点：
  264.0±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  60
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  吗啉基磷酰二氯 、 methoxydimethylsilyl cyanide 以89.4%的产率得到4-morpholinylphosphonous dicyanide
  参考文献：
  名称：

  Organosilicon and organophosphorus compounds with pseudohalide groups. 2. Reactions of alkoxydimethylsilyl cyanides with chlorides of tricoordinated phosphorus

  摘要：

  Reactions of alkoxydimethylsilyl cyanides with some chlorides of tricoordinated phosphorus ("phosphorous chlorides") have been studied. It is shown that, depending on the nature of the phosphorous chloride, the chlorine atoms can either be substituted only for cyano groups, or for alkoxy and cyano groups simultaneously. The results obtained in this work clearly show that alkoxydimethylsilyl cyanides are more reactive reagents for attaching cyano groups to a phosphorus atom than trimethylsilyl cyanide.

  DOI：

  10.1007/bf00959728