(4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V) | 166532-24-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)
• CAS: 166532-24-7
• 化学式: C₁₁H₁₅O₃ReS₃
• 分子量: 477.643
• InChiKey: XCGPEFYCFSKXMO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-甲氧基苯硫酚 、 、 2-巯基乙醚 在 triethylamine 作用下， 以 丙酮 为溶剂， 生成 (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)
  参考文献：
  名称：

  Neutral oxorhenium(V) complexes with tridentate dithiolates and monodentate alkane- or arene-thiolate coligands

  摘要：

  Oxorhenium(v) complexes [ReO(SXS)(SR)] (where HSXSH = 3-thia- or 3-oxa-pentane-1,5-dithiol and RSH = alkane- or arene-thiol) have been synthesized by a ligand exchange reaction of [NEt(3)(CH(2)Ph)][ReOCl4] with a mixture of HSXSH and RSH in methanol-acetonitrile. The compounds were purified by column chromatography or preparative TLC and characterized by elemental analysis, infrared and H-1 NMR spectroscopy. The structure of (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(v) has been determined by X-ray crystallography. The co-ordination is square-pyramidal with the Re atom displaced from the basal plane by 0.728 Angstrom. Co-ordination of the ether group is indicated by the short Re-O(ether) bond distance of 2.103 Angstrom.

  DOI：

  10.1039/dt9950002277