6-Phenylselanyl-3-phenylselanylmethyl-2-oxa-bicyclo[2.2.2]octane | 72991-28-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 6-Phenylselanyl-3-phenylselanylmethyl-2-oxa-bicyclo[2.2.2]octane
• 英文别名: 6-phenylselanyl-3-(phenylselanylmethyl)-2-oxabicyclo[2.2.2]octane
• CAS: 72991-28-7
• 化学式: C₂₀H₂₂OSe₂
• 分子量: 436.314
• InChiKey: GGHUXTRPGBBZHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.82
• 重原子数：
  23.0
• 可旋转键数：
  5.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  4-乙烯基-1-环己烯 、 硒氰酸苯酯 生成 6-Phenylselanyl-3-phenylselanylmethyl-2-oxa-bicyclo[2.2.2]octane
  参考文献：
  名称：

  UEMURA SAKAE; TOSHIMITSU AKIO; AOAI TOSHIAKAI; OKANO MASAYA, CHEM. LETT., 1979, NO 11, 1359-1360

  摘要：

  DOI：

文献信息

• Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins
  作者：Sakae Uemura、Akio Toshimitsu、Toshiaki Aoai、Masaya Okano

  DOI：10.1016/s0040-4039(00)92767-9

  日期：1980.1

  Various cyclic ethers are prepared in good to excellent yields by treating diolefins with phenylselenyl chloride in aqueous acetonitrile. This is the most facile method for organoselenium-induced formation of cyclic ethers from diolefins so far reported.

  通过在乙腈水溶液中用苯基硒烯基氯处理二烯烃，可以以高至极好的收率制备各种环醚。迄今为止，这是由有机烯烃诱导的由二烯烃形成环醚的最简便方法。
• Phenylselenenyl chloride in acetonitrile-water
  作者：Akio Toshimitsu、Toshiaki Aoai、Hiroto Owada、Sakae Uemura、Masaya Okano

  DOI：10.1016/s0040-4020(01)96781-x

  日期：1985.1

  convenient method for hydroxyselenation of olefins so far reported. When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields. From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond

  苯硒基氯与烯烃在乙腈水溶液中的反应以优异的收率提供了β-羟烷基苯基硒化物，为迄今为止报道的烯烃的羟基硒化提供了最方便的方法。当将反应应用于共轭二烯时，以良好至优异的产率获得了单羟基硒化的产物。另一方面，由非共轭二烯以良好至极佳的产率制备了含有两个苯基硒烯基的环状醚，该反应的第一步是一个双键的羟基硒基化。
• Electrochemical Oxyphenylselenation of Dienes
  作者：Rastko D. Vukićević、Miloš Radović、Stanimir Konstantinović

  DOI：10.1007/pl00010143

  日期：1998.12

  The electrochemical oxidation of diphenyl diselenide in the presence of dienes affords the corresponding cyclic beta-phenylselenoethers via an oxyphenylselenation process. The yields of ethers depend on the nature of the diene and on the reaction temperature.
• Oxyselenation of diolefins with phenyl selenocyanate and copper(II) chloride. Synthesis of cyclic ethers
  作者：Akio Toshimitsu、Toshiaki Aoai、Sakae Uemura、Masaya Okano

  DOI：10.1021/jo00328a006

  日期：1981.7
• UEMURA SAKAE; TOSHIMITSU AKIO; AOAI TOSHIAKI; OKANO MASAYA, TETRAHEDRON LETT., 1980, 21, NO 16, 1533-1536
  作者：UEMURA SAKAE、 TOSHIMITSU AKIO、 AOAI TOSHIAKI、 OKANO MASAYA

  DOI：——

  日期：——