bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0) | 1448998-00-2

• 英文名称: bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0)
• 英文别名: bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0)
• CAS: 1448998-00-2
• 化学式: C₅₈H₄₆N₂O₂P₂Pt
• 分子量: 1060.04
• InChiKey: JAIWWDHITPFYNJ-SWJSCKDZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0) 、 二苯基硅烷 以 氘代苯 为溶剂， 生成 (PPh₃)₂PtH(SiHPh₂)
  参考文献：
  名称：

  A new approach to light-gated Pt catalysts for the hydrosilylation

  摘要：

  A new concept for a light-gated transition metal catalyst is presented based on a photo-active moiety in the outer ligand sphere of the complex which on irradiation reacts irreversibly with some part of the inner ligand sphere releasing a free coordination site. The principle is exemplified on a platinum complex for the hydrosilylation. It is proven that the catalytic properties of the complex and the properties of the photo-gate can be fine-tuned on the chemical problem independently of each other. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.04.045
• 作为产物：
  描述：

  2-{phenyl[2-(p-tosyl)hydrazono]methyl}phenyl cinnamate 在 sodium hydride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 1.0h， 生成 bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0)
  参考文献：
  名称：

  A new approach to light-gated Pt catalysts for the hydrosilylation

  摘要：

  A new concept for a light-gated transition metal catalyst is presented based on a photo-active moiety in the outer ligand sphere of the complex which on irradiation reacts irreversibly with some part of the inner ligand sphere releasing a free coordination site. The principle is exemplified on a platinum complex for the hydrosilylation. It is proven that the catalytic properties of the complex and the properties of the photo-gate can be fine-tuned on the chemical problem independently of each other. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.04.045