1,7-di(ethynylphenoxy)-N,N'-(2,6-diisopropylphenyl)perylene-3,4,9,10-tetracarboxylic acid bisimide | 856432-99-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,7-di(ethynylphenoxy)-N,N'-(2,6-diisopropylphenyl)perylene-3,4,9,10-tetracarboxylic acid bisimide
• 英文别名: 7,18-Bis[2,6-di(propan-2-yl)phenyl]-11,22-bis(4-ethynylphenoxy)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
• CAS: 856432-99-0
• 化学式: C₆₄H₅₀N₂O₆
• 分子量: 943.111
• InChiKey: IAOJLMDSIFQLNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.9
• 重原子数：
  72
• 可旋转键数：
  12
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  93.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,7-di[4-(trimethylsilylethynyl)phenoxy]-N,N'-(2,6-diisopropylphenyl)perylene-3,4,9,10-tetracarboxylic acid bisimide 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 0.33h， 以48%的产率得到1,7-di(ethynylphenoxy)-N,N'-(2,6-diisopropylphenyl)perylene-3,4,9,10-tetracarboxylic acid bisimide
  参考文献：
  名称：

  A New Class of Conjugated Polyacetylenes Having Perylene Bisimide Units and Pendant Fullerene or Porphyrin Groups

  摘要：

  A new class of conjugated polyacetylenes having perylene bisimide units and pendant fullerene or porphyrin groups were synthesized and characterized. SEM images displayed the aggregation superstructures of two polymers. The poly(5(0.1)-co-4(0.9)) can form a large quantity of spherical nanoparticles in chloroform because [60]fullerene derivatives have high aggregation tendency due to the pi-pi* stacking of the carbon cage. Furthermore, poly(6(0.1)-co-4(0.9)) can form different aggregation structures in chloroform with the addition of 4,4'-bipyridine (Bipy). In particular, when poly(6(0.1)-co-4(0.9)) was mixed with 2 equiv of Bipy, a uniform cottonlike superstructure was observed. These results indicated that the axial coordination of zinc porphyrin and Bipy played an important role in controlling the aggregation morphologies of poly(6(0.1)-co-4(0.9)) in CHCl3 with the addition of Bipy. More interestingly, the photocurrent measurement showed that the films of these polyacetylenes could produce steady and rapid cathodic photocurrent responses, indicating that efficient charge transfer took place in two donor-acceptor polymers.

  DOI：

  10.1021/ma050434k