| 1039629-44-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 1039629-44-1
• 化学式: C₃₈H₇₈O₆Si₃
• 分子量: 715.29
• InChiKey: MJAUSWJPXROWRJ-IUYKWENYSA-N

反应信息

• 作为反应物：
  描述：

  在 氟化氢吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 以61%的产率得到3-hydroxy-6-[6-(2-hydroxy-3-methylbutyl)-3,5-dimethyl-4-oxotetrahydropyran-2-yl]-4-methylhexanoic acid methyl ester
  参考文献：
  名称：

  Synthetic efforts toward the synthesis of octalactins

  摘要：

  Octalactin B was synthesized from the commercially available methyl-3-butenoate and isobutyraldehyde, using enantioselective allyl- and crotyltitanations to control the stereogenic centers at C3, C4, C7, C8, and C13. Moreover, the two other key-step reactions are a cross-metathesis reaction and a lactonization, using the effective anhydride MNBA, to build up the eight-membered ring lactone. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.04.026
• 作为产物：
  描述：

  在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以49%的产率得到
  参考文献：
  名称：

  Synthetic efforts toward the synthesis of octalactins

  摘要：

  Octalactin B was synthesized from the commercially available methyl-3-butenoate and isobutyraldehyde, using enantioselective allyl- and crotyltitanations to control the stereogenic centers at C3, C4, C7, C8, and C13. Moreover, the two other key-step reactions are a cross-metathesis reaction and a lactonization, using the effective anhydride MNBA, to build up the eight-membered ring lactone. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.04.026