1,4-dichloro-6-methylbenzo[c]phenanthrene | 1097105-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,4-dichloro-6-methylbenzo[c]phenanthrene
• CAS: 1097105-61-7
• 化学式: C₁₉H₁₂Cl₂
• 分子量: 311.21
• InChiKey: KXEQXZGDMDMUOZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1,4-dichloro-6-methylbenzo[c]phenanthrene 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 以96%的产率得到6-bromomethyl-1,4-dichlorobenzo[c]phenanthrene
  参考文献：
  名称：

  Steps toward the synthesis of a geodesic C60H12 end cap for a C3v carbon [6,6]nanotube

  摘要：

  Several shape-persistent carbon-rich nanomolecules with diameters exceeding 1.7 nm have been prepared by the aldol trimerization of 20-carbon aromatic ketones bearing chlorine atoms at Various sites. These C60H27Cl3 and C60H24Cl6 polycyclic aromatic compounds represent attractive intermediates for the synthesis of a geodesic C60H12 end cap of a C-3v carbon [6,6]nanotube. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.087
• 作为产物：
  描述：

  1-(2,5-dichlrophenyl)-2-(2-naphthyl)propene 在 碘 、 methyloxirane 作用下， 以 环己烷 为溶剂， 反应 35.0h， 以62%的产率得到1,4-dichloro-6-methylbenzo[c]phenanthrene
  参考文献：
  名称：

  Steps toward the synthesis of a geodesic C60H12 end cap for a C3v carbon [6,6]nanotube

  摘要：

  Several shape-persistent carbon-rich nanomolecules with diameters exceeding 1.7 nm have been prepared by the aldol trimerization of 20-carbon aromatic ketones bearing chlorine atoms at Various sites. These C60H27Cl3 and C60H24Cl6 polycyclic aromatic compounds represent attractive intermediates for the synthesis of a geodesic C60H12 end cap of a C-3v carbon [6,6]nanotube. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.087