3-[2,2-bis[[4-[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]amino]-3,3-bis[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]carbamoyl]-4-oxobutoxy]methyl]heptoxy]-1-N,1-N,1-N-tris[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]propane-1,1,1-tricarboxamide | 96150-73-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-[2,2-bis[[4-[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]amino]-3,3-bis[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]carbamoyl]-4-oxobutoxy]methyl]heptoxy]-1-N,1-N,1-N-tris[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]propane-1,1,1-tricarboxamide
• CAS: 96150-73-1
• 化学式: C₆₃H₁₁₉N₉O₃₉
• 分子量: 1626.67
• InChiKey: BJZWJRQXTXPZKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -21.6
• 重原子数：
  111
• 可旋转键数：
  64
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  836
• 氢给体数：
  36
• 氢受体数：
  39

反应信息

• 作为产物：
  描述：

  2-{2-[2,2-Bis-(3,3,3-tris-ethoxycarbonyl-propoxymethyl)-heptyloxy]-ethyl}-2-ethoxycarbonyl-malonic acid diethyl ester 、 三羟甲基氨基甲烷 在 potassium carbonate 作用下， 以 二甲基亚砜 为溶剂， 以90%的产率得到3-[2,2-bis[[4-[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]amino]-3,3-bis[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]carbamoyl]-4-oxobutoxy]methyl]heptoxy]-1-N,1-N,1-N-tris[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]propane-1,1,1-tricarboxamide
  参考文献：
  名称：

  Micelles. Part 1. Cascade molecules: a new approach to micelles. A [27]-arborol

  摘要：

  DOI：

  10.1021/jo00211a052

文献信息

• Vinyl-group-containing dendrimer and curable composition
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0899286A1

  公开（公告）日：1999-03-03

  A vinyl-group-containing dendrimer which can serve to decrease the amount of a low-molecular-weight compound having safety and performance problems and which can give a resin composition having a high molecular weight but a low viscosity and having excellent performances as a coating (film), the composition being capable of forming a film (coating) by a conventional coating method using a roll coater or knife coater or by a conventional printing method such as an offset printing method, a gravure printing method, a letterpress printing method or a screen printing method, the composition being curable by any one of conventional triggers such as heating, ultraviolet light, infrared light, electron beam and γ ray, the composition comprising a vinyl-group-containing dendrimer (A) comprising a core portion, branching portions, branches and at least 4 terminal portions and having a vinyl group as a terminal portion and a long-chain group and a curable unsaturated-group-containing compound (B), and the composition comprising a vinyl-group-containing dendrimer (A) obtained by reacting a polyfunctional compound (a) having at least three active-hydrogen-containing groups in a terminal per molecule and having at least five active hydrogen atoms per molecule with a long-chain-group-containing compound (b) having a functional group reactive with an active hydrogen atom so as to leave part of the active hydrogen atoms, thereby obtaining a long-chain-group-containing multi-branched compound (X), and reacting the long-chain-containing multi-branched compound (X) with a vinyl-group-containing compound (c) having a functional group reactive with an active hydrogen atom and a curable unsaturated-group-containing compound (B),

  一种含乙烯基的树枝状聚合物，它可以减少存在安全和性能问题的低分子量化合物的用量，并能得到一种分子量高但粘度低、作为涂层（薄膜）性能优异的树脂组合物，该组合物能够通过使用辊涂机或刀涂机的传统涂布方法或通过胶版印刷法等传统印刷方法形成薄膜（涂层）、该组合物可通过加热、紫外线、红外线、电子束和 γ 射线等任何一种常规触发器固化，该组合物包括含乙烯基的树枝状聚合物 (A)，该树枝状聚合物 (A) 包括一个核心部分、分支部分、至少 4 个末端部分和一个分支部分、和可固化的含不饱和基团的化合物（B）、该组合物包括含乙烯基的树枝状聚合物（A），该树枝状聚合物（A）是通过将每分子末端至少有三个含活性氢基团且每分子至少有五个活性氢原子的多官能团化合物（a）与含长链基团的化合物（b）反应而得到的，该化合物（b）具有与活性氢原子反应的官能团，从而留下部分活性氢原子、从而得到含长链基团的多支链化合物 (X)，并将含长链基团的多支链化合物 (X) 与具有与活性氢原子反应的官能团的含乙烯基基团的化合物 (c) 和可固化的含不饱和基团的化合物 (B) 反应、
• Micelles. Part 1. Cascade molecules: a new approach to micelles. A [27]-arborol
  作者：George R. Newkome、Zhongqi Yao、Gregory R. Baker、Vinod K. Gupta

  DOI：10.1021/jo00211a052

  日期：1985.5